Investigation of lead thiosulfate photolysis in aqueous solutions

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A model of photolysis of PbS2O3 aqueous solutions has been proposed on the basis of identified photolysis products and semiempirical quantum-chemical calculations. The degradation of PbS2O3 starts with the dissociation of the sulfur-sulfur bond in the thiosulfate group via photochemical excitation and transition of the system a whole to the activated state, which is decomposed by the solvent. The interaction of the primary photolysis products with PbS2O3 results in the formation of final products.

Original languageEnglish
Pages (from-to)37-41
Number of pages5
JournalHigh Energy Chemistry
Volume48
Issue number1
DOIs
Publication statusPublished - Jan 2014

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Thiosulfates
Photolysis
photolysis
aqueous solutions
Sulfur
sulfur
products
dissociation
degradation
Degradation
excitation
interactions

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Investigation of lead thiosulfate photolysis in aqueous solutions. / Egorov, N. B.

In: High Energy Chemistry, Vol. 48, No. 1, 01.2014, p. 37-41.

Research output: Contribution to journalArticle

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