Abstract
A model of photolysis of PbS2O3 aqueous solutions has been proposed on the basis of identified photolysis products and semiempirical quantum-chemical calculations. The degradation of PbS2O3 starts with the dissociation of the sulfur-sulfur bond in the thiosulfate group via photochemical excitation and transition of the system a whole to the activated state, which is decomposed by the solvent. The interaction of the primary photolysis products with PbS2O3 results in the formation of final products.
Original language | English |
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Pages (from-to) | 37-41 |
Number of pages | 5 |
Journal | High Energy Chemistry |
Volume | 48 |
Issue number | 1 |
DOIs | |
Publication status | Published - Jan 2014 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry