Investigation of lead thiosulfate photolysis in aqueous solutions

Abstract

A model of photolysis of PbS₂O₃ aqueous solutions has been proposed on the basis of identified photolysis products and semiempirical quantum-chemical calculations. The degradation of PbS₂O₃ starts with the dissociation of the sulfur-sulfur bond in the thiosulfate group via photochemical excitation and transition of the system a whole to the activated state, which is decomposed by the solvent. The interaction of the primary photolysis products with PbS₂O₃ results in the formation of final products.

Original language	English
Pages (from-to)	37-41
Number of pages	5
Journal	High Energy Chemistry
Volume	48
Issue number	1
DOIs	https://doi.org/10.1134/S0018143914010056
Publication status	Published - Jan 2014

ASJC Scopus subject areas

Physical and Theoretical Chemistry

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10.1134/S0018143914010056

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Egorov, N. B. (2014). Investigation of lead thiosulfate photolysis in aqueous solutions. High Energy Chemistry, 48(1), 37-41. https://doi.org/10.1134/S0018143914010056

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abstract = "A model of photolysis of PbS2O3 aqueous solutions has been proposed on the basis of identified photolysis products and semiempirical quantum-chemical calculations. The degradation of PbS2O3 starts with the dissociation of the sulfur-sulfur bond in the thiosulfate group via photochemical excitation and transition of the system a whole to the activated state, which is decomposed by the solvent. The interaction of the primary photolysis products with PbS2O3 results in the formation of final products.",

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