Abstract
A model of photolysis of PbS2O3 aqueous solutions has been proposed on the basis of identified photolysis products and semiempirical quantum-chemical calculations. The degradation of PbS2O3 starts with the dissociation of the sulfur-sulfur bond in the thiosulfate group via photochemical excitation and transition of the system a whole to the activated state, which is decomposed by the solvent. The interaction of the primary photolysis products with PbS2O3 results in the formation of final products.
| Original language | English |
|---|---|
| Pages (from-to) | 37-41 |
| Number of pages | 5 |
| Journal | High Energy Chemistry |
| Volume | 48 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Jan 2014 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
Cite this
Investigation of lead thiosulfate photolysis in aqueous solutions. / Egorov, N. B.
In: High Energy Chemistry, Vol. 48, No. 1, 01.2014, p. 37-41.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Investigation of lead thiosulfate photolysis in aqueous solutions
AU - Egorov, N. B.
PY - 2014/1
Y1 - 2014/1
N2 - A model of photolysis of PbS2O3 aqueous solutions has been proposed on the basis of identified photolysis products and semiempirical quantum-chemical calculations. The degradation of PbS2O3 starts with the dissociation of the sulfur-sulfur bond in the thiosulfate group via photochemical excitation and transition of the system a whole to the activated state, which is decomposed by the solvent. The interaction of the primary photolysis products with PbS2O3 results in the formation of final products.
AB - A model of photolysis of PbS2O3 aqueous solutions has been proposed on the basis of identified photolysis products and semiempirical quantum-chemical calculations. The degradation of PbS2O3 starts with the dissociation of the sulfur-sulfur bond in the thiosulfate group via photochemical excitation and transition of the system a whole to the activated state, which is decomposed by the solvent. The interaction of the primary photolysis products with PbS2O3 results in the formation of final products.
UR - http://www.scopus.com/inward/record.url?scp=84897765044&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84897765044&partnerID=8YFLogxK
U2 - 10.1134/S0018143914010056
DO - 10.1134/S0018143914010056
M3 - Article
VL - 48
SP - 37
EP - 41
JO - High Energy Chemistry
JF - High Energy Chemistry
SN - 0018-1439
IS - 1
ER -