Investigation of hydrogen sorption-desorption processes at gas-phase hydrogenation and defects formation in titanium by means of electron-positron annihilation techniques

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The results of hydrogen sorption and desorption processes investigation at commercially pure titanium alloy during hydrogenation at gas atmosphere are shown in this article. Titanium alloy hydrogenation at temperatures 350, 450 and 550 °C leads to δ-hydrides formation in samples' volume. Hydrogen sorption rates were calculated on the linear parts of sorption curves and equal to 0.15·10-4 wt%/s at 350 °C, 0.86·10-4 wt%/s at 450 °C, 1.55·10-4 wt%/s at 550 °C. Phase transition in titanium-hydrogen system during thermally stimulated hydrogen desorption investigation by the means of short-wave diffraction of synchrotron radiation shows hydrides dissociation until 520-530 °C. Then α→β transition takes place until 690-720 °C and at this temperatures the phase transformation ends and additional hydrogen desorption peak appears in thermally stimulated hydrogen desorption curve. Defect structure at different hydrogen concentration investigation by the means of electron-positron annihilation techniques shows that hydrogen penetration into titanium leads to crystal lattice expansion. It initiates vacancy-type defects formation which reacts with hydrogen and forms defect-hydrogen complexes.

Original languageEnglish
Title of host publicationPositron Annihilation - ICPA-17
PublisherTrans Tech Publications Ltd
Pages317-323
Number of pages7
Volume373 DDF
ISBN (Print)9783038356059
DOIs
Publication statusPublished - 2016
Event17th International Conference onPositron Annihilation, ICPA-17 - Wuhan, China
Duration: 20 Sep 201625 Sep 2016

Conference

Conference17th International Conference onPositron Annihilation, ICPA-17
CountryChina
CityWuhan
Period20.9.1625.9.16

Fingerprint

Positron annihilation
Titanium
positron annihilation
sorption
Hydrogenation
hydrogenation
Sorption
Hydrogen
Desorption
titanium
Gases
desorption
vapor phases
Defects
Electrons
defects
hydrogen
titanium alloys
Titanium alloys
Hydrides

Keywords

  • Electron-positron annihilation
  • Hydrogenation
  • Synchrotron radiation
  • Titanium

ASJC Scopus subject areas

  • Radiation
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Investigation of hydrogen sorption-desorption processes at gas-phase hydrogenation and defects formation in titanium by means of electron-positron annihilation techniques. / Tatyana, Volokitina L.; Roman, Laptev S.; Viktor, Kudiiarov N.; Dmitriy, Gvozdyakov V.; Maria, Babihina N.

Positron Annihilation - ICPA-17. Vol. 373 DDF Trans Tech Publications Ltd, 2016. p. 317-323.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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AU - Tatyana, Volokitina L.

AU - Roman, Laptev S.

AU - Viktor, Kudiiarov N.

AU - Dmitriy, Gvozdyakov V.

AU - Maria, Babihina N.

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N2 - The results of hydrogen sorption and desorption processes investigation at commercially pure titanium alloy during hydrogenation at gas atmosphere are shown in this article. Titanium alloy hydrogenation at temperatures 350, 450 and 550 °C leads to δ-hydrides formation in samples' volume. Hydrogen sorption rates were calculated on the linear parts of sorption curves and equal to 0.15·10-4 wt%/s at 350 °C, 0.86·10-4 wt%/s at 450 °C, 1.55·10-4 wt%/s at 550 °C. Phase transition in titanium-hydrogen system during thermally stimulated hydrogen desorption investigation by the means of short-wave diffraction of synchrotron radiation shows hydrides dissociation until 520-530 °C. Then α→β transition takes place until 690-720 °C and at this temperatures the phase transformation ends and additional hydrogen desorption peak appears in thermally stimulated hydrogen desorption curve. Defect structure at different hydrogen concentration investigation by the means of electron-positron annihilation techniques shows that hydrogen penetration into titanium leads to crystal lattice expansion. It initiates vacancy-type defects formation which reacts with hydrogen and forms defect-hydrogen complexes.

AB - The results of hydrogen sorption and desorption processes investigation at commercially pure titanium alloy during hydrogenation at gas atmosphere are shown in this article. Titanium alloy hydrogenation at temperatures 350, 450 and 550 °C leads to δ-hydrides formation in samples' volume. Hydrogen sorption rates were calculated on the linear parts of sorption curves and equal to 0.15·10-4 wt%/s at 350 °C, 0.86·10-4 wt%/s at 450 °C, 1.55·10-4 wt%/s at 550 °C. Phase transition in titanium-hydrogen system during thermally stimulated hydrogen desorption investigation by the means of short-wave diffraction of synchrotron radiation shows hydrides dissociation until 520-530 °C. Then α→β transition takes place until 690-720 °C and at this temperatures the phase transformation ends and additional hydrogen desorption peak appears in thermally stimulated hydrogen desorption curve. Defect structure at different hydrogen concentration investigation by the means of electron-positron annihilation techniques shows that hydrogen penetration into titanium leads to crystal lattice expansion. It initiates vacancy-type defects formation which reacts with hydrogen and forms defect-hydrogen complexes.

KW - Electron-positron annihilation

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