Investigation of chlorine valence electron density in SnCl4L2, SbCl5L and TiCl4L2 complexes

O. Kh Poleshchuk, V. P. Elin, J. Koput, B. Nogaj, G. N. Dolenko

    Research output: Contribution to journal › Article

    5 Citations (Scopus)

    Abstract

    The electron density on valence orbitals of chlorine atoms in SnCl4L2, SbCl5L and TiCl4L2 complexes has been investigated by NQR and X-ray fluorescence spectroscopy. It has been established that the increase in the negative charge on the chlorine atoms in the acceptor part of the complex can be explained only when changes in the acceptor geometry are taken into account.

    Original languageEnglish
    Pages (from-to)107-110
    Number of pages4
    JournalJournal of Molecular Structure
    Volume344
    Issue number1-2
    Publication statusPublished - 1 Jan 1995

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    Chlorine
    Carrier concentration
    Atoms
    Geometry
    X-Ray Emission Spectrometry

    ASJC Scopus subject areas

    • Spectroscopy
    • Organic Chemistry
    • Inorganic Chemistry
    • Analytical Chemistry

    Cite this

    Poleshchuk, O. K., Elin, V. P., Koput, J., Nogaj, B., & Dolenko, G. N. (1995). Investigation of chlorine valence electron density in SnCl4L2, SbCl5L and TiCl4L2 complexes. Journal of Molecular Structure, 344(1-2), 107-110.

    Investigation of chlorine valence electron density in SnCl4L2, SbCl5L and TiCl4L2 complexes. / Poleshchuk, O. Kh; Elin, V. P.; Koput, J.; Nogaj, B.; Dolenko, G. N.

    In: Journal of Molecular Structure, Vol. 344, No. 1-2, 01.01.1995, p. 107-110.

    Research output: Contribution to journal › Article

    Poleshchuk, OK, Elin, VP, Koput, J, Nogaj, B & Dolenko, GN 1995, 'Investigation of chlorine valence electron density in SnCl4L2, SbCl5L and TiCl4L2 complexes', Journal of Molecular Structure, vol. 344, no. 1-2, pp. 107-110.
    Poleshchuk OK, Elin VP, Koput J, Nogaj B, Dolenko GN. Investigation of chlorine valence electron density in SnCl4L2, SbCl5L and TiCl4L2 complexes. Journal of Molecular Structure. 1995 Jan 1;344(1-2):107-110.
    Poleshchuk, O. Kh ; Elin, V. P. ; Koput, J. ; Nogaj, B. ; Dolenko, G. N. / Investigation of chlorine valence electron density in SnCl4L2, SbCl5L and TiCl4L2 complexes. In: Journal of Molecular Structure. 1995 ; Vol. 344, No. 1-2. pp. 107-110.
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    AU - Dolenko, G. N.

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    AB - The electron density on valence orbitals of chlorine atoms in SnCl4L2, SbCl5L and TiCl4L2 complexes has been investigated by NQR and X-ray fluorescence spectroscopy. It has been established that the increase in the negative charge on the chlorine atoms in the acceptor part of the complex can be explained only when changes in the acceptor geometry are taken into account.

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