Abstract
The electronic structure of pentafluorophenyl-substituted silanes ArnSi(CH3)4-n (Ar = C6H5, C6F5, 4-FC6H4, 2,3,5,6-F4C5N; n = 1; Ar = C6H5, C6F5, n = 2, 4) was studied by X-ray emission and He(I) photoelectron spectroscopy. The He(I) photoelectron spectra were measured and interpreted on the basis of MNDO calculations, analysis of the p-fluoro effect, and relative intensities. Substitution of C6F5 for C6H5 in aryltrimethyl- and diaryldimethylsilanes results in enhanced π interaction between the aryl and Si(CH3)n groups (n = 2, 3) by higher π levels and has almost no effect on the charge on the silicon atom.
| Original language | English |
|---|---|
| Pages (from-to) | 101-110 |
| Number of pages | 10 |
| Journal | Russian Journal of General Chemistry |
| Volume | 70 |
| Issue number | 1 |
| Publication status | Published - 2000 |
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Cite this
Intramolecular interactions in aromatic compounds : V. Electronic structure of polyfluoroaromatic silanes and related hydrocarbons. / Krupoder, S. A.; Okotrub, A. V.; Villem, N. V.; Villem, J. J.; Furin, G. G.; Salakhutdinov, N. F.; Poleshchuk, O. Kh.
In: Russian Journal of General Chemistry, Vol. 70, No. 1, 2000, p. 101-110.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Intramolecular interactions in aromatic compounds
T2 - V. Electronic structure of polyfluoroaromatic silanes and related hydrocarbons
AU - Krupoder, S. A.
AU - Okotrub, A. V.
AU - Villem, N. V.
AU - Villem, J. J.
AU - Furin, G. G.
AU - Salakhutdinov, N. F.
AU - Poleshchuk, O. Kh
PY - 2000
Y1 - 2000
N2 - The electronic structure of pentafluorophenyl-substituted silanes ArnSi(CH3)4-n (Ar = C6H5, C6F5, 4-FC6H4, 2,3,5,6-F4C5N; n = 1; Ar = C6H5, C6F5, n = 2, 4) was studied by X-ray emission and He(I) photoelectron spectroscopy. The He(I) photoelectron spectra were measured and interpreted on the basis of MNDO calculations, analysis of the p-fluoro effect, and relative intensities. Substitution of C6F5 for C6H5 in aryltrimethyl- and diaryldimethylsilanes results in enhanced π interaction between the aryl and Si(CH3)n groups (n = 2, 3) by higher π levels and has almost no effect on the charge on the silicon atom.
AB - The electronic structure of pentafluorophenyl-substituted silanes ArnSi(CH3)4-n (Ar = C6H5, C6F5, 4-FC6H4, 2,3,5,6-F4C5N; n = 1; Ar = C6H5, C6F5, n = 2, 4) was studied by X-ray emission and He(I) photoelectron spectroscopy. The He(I) photoelectron spectra were measured and interpreted on the basis of MNDO calculations, analysis of the p-fluoro effect, and relative intensities. Substitution of C6F5 for C6H5 in aryltrimethyl- and diaryldimethylsilanes results in enhanced π interaction between the aryl and Si(CH3)n groups (n = 2, 3) by higher π levels and has almost no effect on the charge on the silicon atom.
UR - http://www.scopus.com/inward/record.url?scp=0034336286&partnerID=8YFLogxK
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M3 - Article
AN - SCOPUS:0034336286
VL - 70
SP - 101
EP - 110
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 1
ER -