Intermolecular interactions in poly(methyl methacrylate) modified with silver, copper, or neodymium trifluoroacetates

G. M. Mokrousov, Nataliya Airatovna Gavrilenko, N. G. Garber, M. A. Gavrilenko

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Abstract

Intermolecular interactions of poly(methyl methacrylate) with silver, copper, and neodymium trifluoroacetates were studied by gas-liquid chromatography. It was found that the polymer modified with these metal salts retains the ability to participate in donor-acceptor complexation with nucleophilic compounds. This is a result of the delocalization of vacant orbitals of the metal ion during the competitive interaction between the trifluoroacetate anion and the polymeric matrix.

Original languageEnglish
Pages (from-to)1023-1025
Number of pages3
JournalRussian Journal of Physical Chemistry A
Volume75
Issue number6
Publication statusPublished - Jun 2001

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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