Abstract
Joint electrochemical oxidation of copper and aluminum using alternating current (AC) was performed. The electrolysis products were dried on air (method carbonate) and at the residual pressure of 3-5 kPa (oxide method). Cu-Al layered double hydroxide (Cu-Al/LDH) is formed at air carbonization. Oxide method saves copper (I) oxide. Heat treatment causes the decomposition of LDH to CuO and Al2O3 as well as Cu2O oxidation to CuO. CuO/Al2O3 has a number of catalytic applications. Copper-aluminum spinel (CuAl2O4) is the product of solid-phase interaction of copper and aluminum oxides. IR-spectra revealed that oxide method provides the boehmite dehydration and metal oxides interaction at lower temperature despite the fact that the poorly crystallized copper (II) oxide is formed at LDH decomposition.
| Original language | English |
|---|---|
| Title of host publication | Advanced Materials for Technical and Medical Purpose |
| Publisher | Trans Tech Publications Ltd |
| Pages | 65-70 |
| Number of pages | 6 |
| Volume | 712 |
| ISBN (Print) | 9783035710649 |
| DOIs | |
| Publication status | Published - 2016 |
| Event | Workshop on Advanced Materials for Technical and Medical Purpose, AMTMP-2016 - Tomsk, Russian Federation Duration: 15 Feb 2016 → 17 Feb 2016 |
Publication series
| Name | Key Engineering Materials |
|---|---|
| Volume | 712 |
| ISSN (Print) | 1013-9826 |
Conference
| Conference | Workshop on Advanced Materials for Technical and Medical Purpose, AMTMP-2016 |
|---|---|
| Country | Russian Federation |
| City | Tomsk |
| Period | 15.2.16 → 17.2.16 |
Fingerprint
Keywords
- Alternating current (AC)
- Copper oxide
- Electrolysis
- Heat treatment
- IR-spectroscopy
- Layered double hydroxide
ASJC Scopus subject areas
- Materials Science(all)
- Mechanics of Materials
- Mechanical Engineering
Cite this
Infrared spectra investigation of CuO-Al2O3 precursors produced by electrochemical oxidation of copper and aluminum using alternating current. / Usoltseva, Natalia Vasilievna; Korobochkin, V. V.; Dolinina, Alesya Sergeevna; Ustyugov, A. M.
Advanced Materials for Technical and Medical Purpose. Vol. 712 Trans Tech Publications Ltd, 2016. p. 65-70 (Key Engineering Materials; Vol. 712).Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Infrared spectra investigation of CuO-Al2O3 precursors produced by electrochemical oxidation of copper and aluminum using alternating current
AU - Usoltseva, Natalia Vasilievna
AU - Korobochkin, V. V.
AU - Dolinina, Alesya Sergeevna
AU - Ustyugov, A. M.
PY - 2016
Y1 - 2016
N2 - Joint electrochemical oxidation of copper and aluminum using alternating current (AC) was performed. The electrolysis products were dried on air (method carbonate) and at the residual pressure of 3-5 kPa (oxide method). Cu-Al layered double hydroxide (Cu-Al/LDH) is formed at air carbonization. Oxide method saves copper (I) oxide. Heat treatment causes the decomposition of LDH to CuO and Al2O3 as well as Cu2O oxidation to CuO. CuO/Al2O3 has a number of catalytic applications. Copper-aluminum spinel (CuAl2O4) is the product of solid-phase interaction of copper and aluminum oxides. IR-spectra revealed that oxide method provides the boehmite dehydration and metal oxides interaction at lower temperature despite the fact that the poorly crystallized copper (II) oxide is formed at LDH decomposition.
AB - Joint electrochemical oxidation of copper and aluminum using alternating current (AC) was performed. The electrolysis products were dried on air (method carbonate) and at the residual pressure of 3-5 kPa (oxide method). Cu-Al layered double hydroxide (Cu-Al/LDH) is formed at air carbonization. Oxide method saves copper (I) oxide. Heat treatment causes the decomposition of LDH to CuO and Al2O3 as well as Cu2O oxidation to CuO. CuO/Al2O3 has a number of catalytic applications. Copper-aluminum spinel (CuAl2O4) is the product of solid-phase interaction of copper and aluminum oxides. IR-spectra revealed that oxide method provides the boehmite dehydration and metal oxides interaction at lower temperature despite the fact that the poorly crystallized copper (II) oxide is formed at LDH decomposition.
KW - Alternating current (AC)
KW - Copper oxide
KW - Electrolysis
KW - Heat treatment
KW - IR-spectroscopy
KW - Layered double hydroxide
UR - http://www.scopus.com/inward/record.url?scp=84990846999&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84990846999&partnerID=8YFLogxK
U2 - 10.4028/www.scientific.net/KEM.712.65
DO - 10.4028/www.scientific.net/KEM.712.65
M3 - Conference contribution
AN - SCOPUS:84990846999
SN - 9783035710649
VL - 712
T3 - Key Engineering Materials
SP - 65
EP - 70
BT - Advanced Materials for Technical and Medical Purpose
PB - Trans Tech Publications Ltd
ER -