Influence of ultra-violet radiation on sublimation energy of silver chloride (AgCl)

Research output: Chapter in Book/Report/Conference proceedingConference contribution

9 Citations (Scopus)

Abstract

Influence of silver chloride synthesis conditions on its heat of sublimation after ultraviolet irradiation was explored. It was determined that silver chloride synthesized in excess of silver ions after irradiation was characterized by heat of sublimation about 6813 J/g, which meant that the original value increased in ∼ 1.8 times. At the same time silver chloride synthesized in excess of chloride ions was characterized by decrease in value of heat of sublimation by ∼ 2 times. Growth of heat of sublimation of silver chloride with excess of silver ions is connected with energy expenditure on sublimation due to decrease in proportion of surface which is not covered with silver. Reduction of heat of sublimation of silver chloride with excess of chloride ions is explained by absence of silver solid surface film and catalytic effect of silver klasters formed during the process of irradiation.

Original languageEnglish
Title of host publicationHigh Technology
Subtitle of host publicationResearch and Applications, 2015
PublisherTrans Tech Publications Ltd
Pages735-738
Number of pages4
ISBN (Print)9783038357087
DOIs
Publication statusPublished - 1 Jan 2016
Event4th International Conference for Young Scientists High Technology: Research and Applications, HTRA 2015 - Tomsk, Russian Federation
Duration: 21 Apr 201524 Apr 2015

Publication series

NameKey Engineering Materials
Volume685
ISSN (Print)1013-9826

Conference

Conference4th International Conference for Young Scientists High Technology: Research and Applications, HTRA 2015
CountryRussian Federation
CityTomsk
Period21.4.1524.4.15

Fingerprint

Sublimation
Ultraviolet radiation
Silver
Ions
Irradiation
Chlorides
silver chloride
Hot Temperature

Keywords

  • Electron microscopy
  • Heat of sublimation
  • Klaster
  • Lattice
  • Silver chloride
  • Silver ions
  • Thermal analysis
  • Ultra-violet radiation

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Mostovshchikov, A. V., Ilyin, A. P., & Barabash, N. S. (2016). Influence of ultra-violet radiation on sublimation energy of silver chloride (AgCl). In High Technology: Research and Applications, 2015 (pp. 735-738). (Key Engineering Materials; Vol. 685). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/KEM.685.735

Influence of ultra-violet radiation on sublimation energy of silver chloride (AgCl). / Mostovshchikov, Andrei V.; Ilyin, Alexander P.; Barabash, Nadezhda S.

High Technology: Research and Applications, 2015. Trans Tech Publications Ltd, 2016. p. 735-738 (Key Engineering Materials; Vol. 685).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Mostovshchikov, AV, Ilyin, AP & Barabash, NS 2016, Influence of ultra-violet radiation on sublimation energy of silver chloride (AgCl). in High Technology: Research and Applications, 2015. Key Engineering Materials, vol. 685, Trans Tech Publications Ltd, pp. 735-738, 4th International Conference for Young Scientists High Technology: Research and Applications, HTRA 2015, Tomsk, Russian Federation, 21.4.15. https://doi.org/10.4028/www.scientific.net/KEM.685.735
Mostovshchikov AV, Ilyin AP, Barabash NS. Influence of ultra-violet radiation on sublimation energy of silver chloride (AgCl). In High Technology: Research and Applications, 2015. Trans Tech Publications Ltd. 2016. p. 735-738. (Key Engineering Materials). https://doi.org/10.4028/www.scientific.net/KEM.685.735
Mostovshchikov, Andrei V. ; Ilyin, Alexander P. ; Barabash, Nadezhda S. / Influence of ultra-violet radiation on sublimation energy of silver chloride (AgCl). High Technology: Research and Applications, 2015. Trans Tech Publications Ltd, 2016. pp. 735-738 (Key Engineering Materials).
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