Abstract
Tb3+- doped high silica glass was prepared by sintering porous glass. The density, valence state and amount of Tb, transmittance, photoexcitation spectra, photoluminescence spectra, and cathodoluminescence spectra (CL) were recorded and the luminescence decay kinetics analyzed in details. These results show that the doping concentration in high silica glass is in direct proportion to the concentration in solution, and the density increases with the increasing concentration of rare earth ions as well as the intensity of emission spectrum. The largest emission intensity of 0.2 mol/L is more than 2 times higher than the intensity of the 0.05 mol/L. Besides, the “red” shift phenomenon could be distinguished clearly in the transmittance spectra. There is a broad band at the “red” region in the CL spectra. The decay time which is in the millisecond range in different spectral range were measured and analyzed revealing that the decay time of 5D3 is shorter than that of 5D4.
| Original language | English |
|---|---|
| Pages (from-to) | 606-610 |
| Number of pages | 5 |
| Journal | Optical Materials |
| Volume | 86 |
| DOIs | |
| Publication status | Published - 1 Dec 2018 |
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Keywords
- High silica porous glass
- Luminescent properties
- Rare earth ions
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Computer Science(all)
- Atomic and Molecular Physics, and Optics
- Electrical and Electronic Engineering
Cite this
Influence of the Tb3+ concentration on the luminescent properties of high silica glass. / Chen, Q.; Valiev, D.; Stepanov, S.; Ding, J.; Liu, L.; Li, C.; Lin, H.; Zhou, Y.; Zeng, F.
In: Optical Materials, Vol. 86, 01.12.2018, p. 606-610.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Influence of the Tb3+ concentration on the luminescent properties of high silica glass
AU - Chen, Q.
AU - Valiev, D.
AU - Stepanov, S.
AU - Ding, J.
AU - Liu, L.
AU - Li, C.
AU - Lin, H.
AU - Zhou, Y.
AU - Zeng, F.
PY - 2018/12/1
Y1 - 2018/12/1
N2 - Tb3+- doped high silica glass was prepared by sintering porous glass. The density, valence state and amount of Tb, transmittance, photoexcitation spectra, photoluminescence spectra, and cathodoluminescence spectra (CL) were recorded and the luminescence decay kinetics analyzed in details. These results show that the doping concentration in high silica glass is in direct proportion to the concentration in solution, and the density increases with the increasing concentration of rare earth ions as well as the intensity of emission spectrum. The largest emission intensity of 0.2 mol/L is more than 2 times higher than the intensity of the 0.05 mol/L. Besides, the “red” shift phenomenon could be distinguished clearly in the transmittance spectra. There is a broad band at the “red” region in the CL spectra. The decay time which is in the millisecond range in different spectral range were measured and analyzed revealing that the decay time of 5D3 is shorter than that of 5D4.
AB - Tb3+- doped high silica glass was prepared by sintering porous glass. The density, valence state and amount of Tb, transmittance, photoexcitation spectra, photoluminescence spectra, and cathodoluminescence spectra (CL) were recorded and the luminescence decay kinetics analyzed in details. These results show that the doping concentration in high silica glass is in direct proportion to the concentration in solution, and the density increases with the increasing concentration of rare earth ions as well as the intensity of emission spectrum. The largest emission intensity of 0.2 mol/L is more than 2 times higher than the intensity of the 0.05 mol/L. Besides, the “red” shift phenomenon could be distinguished clearly in the transmittance spectra. There is a broad band at the “red” region in the CL spectra. The decay time which is in the millisecond range in different spectral range were measured and analyzed revealing that the decay time of 5D3 is shorter than that of 5D4.
KW - High silica porous glass
KW - Luminescent properties
KW - Rare earth ions
UR - http://www.scopus.com/inward/record.url?scp=85056650367&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85056650367&partnerID=8YFLogxK
U2 - 10.1016/j.optmat.2018.10.008
DO - 10.1016/j.optmat.2018.10.008
M3 - Article
AN - SCOPUS:85056650367
VL - 86
SP - 606
EP - 610
JO - Optical Materials
JF - Optical Materials
SN - 0925-3467
ER -