Abstract
A procedure of bulk modification of aluminum oxhydroxide AlOOH during synthesis using manganese(II) ion as the modifying agent was studied. The physicochemical properties of the modified AlOOH fiber were examined. It was found that the presence of manganese(II) ions in solution affected the composition of the products of the reaction between aluminum nanopowder and "liquid water." The phase composition of the reaction products was examined by X-ray diffraction and differential thermal analysis techniques. It was shown that, for solutions with the manganese ion concentration varying from 0.02 × 10-3 to 40 × 10-3 mol l-1, the degree of amorphicity and the proportion of the AlOOH phase tended to increase. A modification mechanism involving the participation of manganese ions in the AlOOH nanofiber growth process was proposed.
| Original language | English |
|---|---|
| Pages (from-to) | 360-365 |
| Number of pages | 6 |
| Journal | Russian Journal of Applied Chemistry |
| Volume | 86 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - Mar 2013 |
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ASJC Scopus subject areas
- Chemistry(all)
- Chemical Engineering(all)
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Influence of the modification process on the properties of AlOOH nanofibers. / Gryaznova, Elena Nikolaevna; Shiyan, L. N.; Yavorovskii, N. A.; Korobochkin, V. V.
In: Russian Journal of Applied Chemistry, Vol. 86, No. 3, 03.2013, p. 360-365.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Influence of the modification process on the properties of AlOOH nanofibers
AU - Gryaznova, Elena Nikolaevna
AU - Shiyan, L. N.
AU - Yavorovskii, N. A.
AU - Korobochkin, V. V.
PY - 2013/3
Y1 - 2013/3
N2 - A procedure of bulk modification of aluminum oxhydroxide AlOOH during synthesis using manganese(II) ion as the modifying agent was studied. The physicochemical properties of the modified AlOOH fiber were examined. It was found that the presence of manganese(II) ions in solution affected the composition of the products of the reaction between aluminum nanopowder and "liquid water." The phase composition of the reaction products was examined by X-ray diffraction and differential thermal analysis techniques. It was shown that, for solutions with the manganese ion concentration varying from 0.02 × 10-3 to 40 × 10-3 mol l-1, the degree of amorphicity and the proportion of the AlOOH phase tended to increase. A modification mechanism involving the participation of manganese ions in the AlOOH nanofiber growth process was proposed.
AB - A procedure of bulk modification of aluminum oxhydroxide AlOOH during synthesis using manganese(II) ion as the modifying agent was studied. The physicochemical properties of the modified AlOOH fiber were examined. It was found that the presence of manganese(II) ions in solution affected the composition of the products of the reaction between aluminum nanopowder and "liquid water." The phase composition of the reaction products was examined by X-ray diffraction and differential thermal analysis techniques. It was shown that, for solutions with the manganese ion concentration varying from 0.02 × 10-3 to 40 × 10-3 mol l-1, the degree of amorphicity and the proportion of the AlOOH phase tended to increase. A modification mechanism involving the participation of manganese ions in the AlOOH nanofiber growth process was proposed.
UR - http://www.scopus.com/inward/record.url?scp=84877792452&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84877792452&partnerID=8YFLogxK
U2 - 10.1134/S1070427213030129
DO - 10.1134/S1070427213030129
M3 - Article
AN - SCOPUS:84877792452
VL - 86
SP - 360
EP - 365
JO - Russian Journal of Applied Chemistry
JF - Russian Journal of Applied Chemistry
SN - 1070-4272
IS - 3
ER -