Influence of the catalyst preparation on properties of chromium- magnesium catalysts for freon 125 synthesis

Aleksandr Zirka, Ludmila Simonova, Natalia Kosova, Irina Kurzina, Sergey Reshetnikov

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Abstract

    The effect of the chromium-magnesium precursor preparation techniques on the physicochemical properties (BET surface area, total pore volume, mean pore diameter) and catalysts activity in the gas-phase hydrofluorination of perchloroethylene to pentafluoroethane (Freon 125) was studied. Kinetics of the catalytic reactions was studied for the most active catalyst. Based on the experimental data, the pathway of perchloroethylene fluorination with HF was suggested.

    Original languageEnglish
    Title of host publicationKey Engineering Materials
    PublisherTrans Tech Publications Ltd
    Pages152-155
    Number of pages4
    Volume670
    ISBN (Print)9783038356127
    DOIs
    Publication statusPublished - 2015
    EventInternational Scientific Conference on Multifunctional Chemical Materials and Technologies, MCMT 2015 - Tomsk, Russian Federation
    Duration: 21 May 201522 May 2015

    Publication series

    NameKey Engineering Materials
    Volume670
    ISSN (Print)10139826

    Other

    OtherInternational Scientific Conference on Multifunctional Chemical Materials and Technologies, MCMT 2015
    CountryRussian Federation
    CityTomsk
    Period21.5.1522.5.15

    Fingerprint

    Chlorofluorocarbons
    Tetrachloroethylene
    Fluorination
    Chromium
    Magnesium
    Surface properties
    Catalyst activity
    Catalysts
    Kinetics
    Gases
    pentafluoroethane

    Keywords

    • Catalyst preparation
    • Freon
    • Hydrofluorination
    • Pentafluoroethane

    ASJC Scopus subject areas

    • Materials Science(all)
    • Mechanics of Materials
    • Mechanical Engineering

    Cite this

    Zirka, A., Simonova, L., Kosova, N., Kurzina, I., & Reshetnikov, S. (2015). Influence of the catalyst preparation on properties of chromium- magnesium catalysts for freon 125 synthesis. In Key Engineering Materials (Vol. 670, pp. 152-155). (Key Engineering Materials; Vol. 670). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/KEM.670.152

    Influence of the catalyst preparation on properties of chromium- magnesium catalysts for freon 125 synthesis. / Zirka, Aleksandr; Simonova, Ludmila; Kosova, Natalia; Kurzina, Irina; Reshetnikov, Sergey.

    Key Engineering Materials. Vol. 670 Trans Tech Publications Ltd, 2015. p. 152-155 (Key Engineering Materials; Vol. 670).

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Zirka, A, Simonova, L, Kosova, N, Kurzina, I & Reshetnikov, S 2015, Influence of the catalyst preparation on properties of chromium- magnesium catalysts for freon 125 synthesis. in Key Engineering Materials. vol. 670, Key Engineering Materials, vol. 670, Trans Tech Publications Ltd, pp. 152-155, International Scientific Conference on Multifunctional Chemical Materials and Technologies, MCMT 2015, Tomsk, Russian Federation, 21.5.15. https://doi.org/10.4028/www.scientific.net/KEM.670.152
    Zirka A, Simonova L, Kosova N, Kurzina I, Reshetnikov S. Influence of the catalyst preparation on properties of chromium- magnesium catalysts for freon 125 synthesis. In Key Engineering Materials. Vol. 670. Trans Tech Publications Ltd. 2015. p. 152-155. (Key Engineering Materials). https://doi.org/10.4028/www.scientific.net/KEM.670.152
    Zirka, Aleksandr ; Simonova, Ludmila ; Kosova, Natalia ; Kurzina, Irina ; Reshetnikov, Sergey. / Influence of the catalyst preparation on properties of chromium- magnesium catalysts for freon 125 synthesis. Key Engineering Materials. Vol. 670 Trans Tech Publications Ltd, 2015. pp. 152-155 (Key Engineering Materials).
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