Influence of plasma immersion titanium implantation on hydrogenation and mechanical properties of Zr-2.5Nb

Abstract

This paper describes the effect of plasma immersion ion implantation (PIII) of titanium on hydrogenation behavior and mechanical properties of Zr-2.5Nb alloy. Surface morphology and depth distribution of elements in the surface layer of the samples were analyzed by scanning electron (SEM) and atomic force microscopy (AFM), and glow-discharge optical emission spectroscopy (GDOES). Hydrogenation was performed at 673 K temperature and 2 atm pressure. It was found that after titanium implantation a diffusion barrier is formed, accumulating hydrogen and preventing hydrogen penetration in the sample volume. The microdroplet content significantly influences the hydrogenation behavior of the zirconium alloy. Hydrogen sorption rate decreased 18.3 times and 4.3 times using filtered and unfiltered PIII, respectively. The mechanical properties of titanium-implanted zirconium layer were improved. The degradation of the mechanical properties after hydrogenation was revealed.

Original language	English
Pages (from-to)	142-148
Number of pages	7
Journal	Applied Surface Science
Volume	370
DOIs	https://doi.org/10.1016/j.apsusc.2016.02.149
Publication status	Published - 1 May 2016

Keywords

Hydrogenation
Mechanical properties
Plasma immersion ion implantation
Titanium ion implantation
Zirconium

ASJC Scopus subject areas

Surfaces, Coatings and Films

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10.1016/j.apsusc.2016.02.149

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@article{8657600eb8fa4545b65552fa4cbefbed,

title = "Influence of plasma immersion titanium implantation on hydrogenation and mechanical properties of Zr-2.5Nb",

abstract = "This paper describes the effect of plasma immersion ion implantation (PIII) of titanium on hydrogenation behavior and mechanical properties of Zr-2.5Nb alloy. Surface morphology and depth distribution of elements in the surface layer of the samples were analyzed by scanning electron (SEM) and atomic force microscopy (AFM), and glow-discharge optical emission spectroscopy (GDOES). Hydrogenation was performed at 673 K temperature and 2 atm pressure. It was found that after titanium implantation a diffusion barrier is formed, accumulating hydrogen and preventing hydrogen penetration in the sample volume. The microdroplet content significantly influences the hydrogenation behavior of the zirconium alloy. Hydrogen sorption rate decreased 18.3 times and 4.3 times using filtered and unfiltered PIII, respectively. The mechanical properties of titanium-implanted zirconium layer were improved. The degradation of the mechanical properties after hydrogenation was revealed.",

keywords = "Hydrogenation, Mechanical properties, Plasma immersion ion implantation, Titanium ion implantation, Zirconium",

author = "Kashkarov, {E. B.} and Nikitenkov, {N. N.} and Syrtanov, {M. S.} and Sutygina, {A. N.} and Shulepov, {I. A.} and Lider, {A. M.}",

year = "2016",

month = may,

day = "1",

doi = "10.1016/j.apsusc.2016.02.149",

language = "English",

volume = "370",

pages = "142--148",

journal = "Applied Surface Science",

issn = "0169-4332",

publisher = "Elsevier",

}

TY - JOUR

T1 - Influence of plasma immersion titanium implantation on hydrogenation and mechanical properties of Zr-2.5Nb

AU - Kashkarov, E. B.

AU - Nikitenkov, N. N.

AU - Syrtanov, M. S.

AU - Sutygina, A. N.

AU - Shulepov, I. A.

AU - Lider, A. M.

PY - 2016/5/1

Y1 - 2016/5/1

N2 - This paper describes the effect of plasma immersion ion implantation (PIII) of titanium on hydrogenation behavior and mechanical properties of Zr-2.5Nb alloy. Surface morphology and depth distribution of elements in the surface layer of the samples were analyzed by scanning electron (SEM) and atomic force microscopy (AFM), and glow-discharge optical emission spectroscopy (GDOES). Hydrogenation was performed at 673 K temperature and 2 atm pressure. It was found that after titanium implantation a diffusion barrier is formed, accumulating hydrogen and preventing hydrogen penetration in the sample volume. The microdroplet content significantly influences the hydrogenation behavior of the zirconium alloy. Hydrogen sorption rate decreased 18.3 times and 4.3 times using filtered and unfiltered PIII, respectively. The mechanical properties of titanium-implanted zirconium layer were improved. The degradation of the mechanical properties after hydrogenation was revealed.

AB - This paper describes the effect of plasma immersion ion implantation (PIII) of titanium on hydrogenation behavior and mechanical properties of Zr-2.5Nb alloy. Surface morphology and depth distribution of elements in the surface layer of the samples were analyzed by scanning electron (SEM) and atomic force microscopy (AFM), and glow-discharge optical emission spectroscopy (GDOES). Hydrogenation was performed at 673 K temperature and 2 atm pressure. It was found that after titanium implantation a diffusion barrier is formed, accumulating hydrogen and preventing hydrogen penetration in the sample volume. The microdroplet content significantly influences the hydrogenation behavior of the zirconium alloy. Hydrogen sorption rate decreased 18.3 times and 4.3 times using filtered and unfiltered PIII, respectively. The mechanical properties of titanium-implanted zirconium layer were improved. The degradation of the mechanical properties after hydrogenation was revealed.

KW - Hydrogenation

KW - Mechanical properties

KW - Plasma immersion ion implantation

KW - Titanium ion implantation

KW - Zirconium

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U2 - 10.1016/j.apsusc.2016.02.149

DO - 10.1016/j.apsusc.2016.02.149

M3 - Article

AN - SCOPUS:84959360465

VL - 370

SP - 142

EP - 148

JO - Applied Surface Science

JF - Applied Surface Science

SN - 0169-4332

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