Influence of Conditions of Cryogenic Molybdenite Grinding on the Activity of Bulk Sulfide Hydrotreating Catalysts

Abstract

Abstract: The milling of molybdenite under cryogenic conditions in argon has been performed for the first time, and the physicochemical properties of its samples, their catalytic activity in model reactions of hydrodesulfurization of dibenzothiophene and diesel components, and the ability to initiate the isopropylbenzene oxidation reaction have been studied. The samples have been found to exhibit high catalytic activity.

Original language	English
Pages (from-to)	365-372
Number of pages	8
Journal	Petroleum Chemistry
Volume	60
Issue number	3
DOIs	https://doi.org/10.1134/S0965544120030147
Publication status	Published - 1 Mar 2020

Keywords

bulk sulfide catalysts
cryogenic dispersion
model hydrodesulfurization and oxidation reactions
molybdenite

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Fuel Technology
Energy Engineering and Power Technology
Geochemistry and Petrology

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Mikubaeva, E. V., Akimov, A. S., Zhuravkov, S. P., Sizova, N. V., Vosmerikov, A. V., Prosvirin, I. P., Zaikovskii, V. I., Uimin, M. A., Maikov, V. V., Lisovaya, K. N., & Fedushchak, T. A. (2020). Influence of Conditions of Cryogenic Molybdenite Grinding on the Activity of Bulk Sulfide Hydrotreating Catalysts. Petroleum Chemistry, 60(3), 365-372. https://doi.org/10.1134/S0965544120030147

Influence of Conditions of Cryogenic Molybdenite Grinding on the Activity of Bulk Sulfide Hydrotreating Catalysts. / Mikubaeva, E. V.; Akimov, A. S.; Zhuravkov, S. P.; Sizova, N. V.; Vosmerikov, A. V.; Prosvirin, I. P.; Zaikovskii, V. I.; Uimin, M. A.; Maikov, V. V.; Lisovaya, K. N.; Fedushchak, T. A.

In: Petroleum Chemistry, Vol. 60, No. 3, 01.03.2020, p. 365-372.

Research output: Contribution to journal › Article › peer-review

Mikubaeva, E. V. ; Akimov, A. S. ; Zhuravkov, S. P. ; Sizova, N. V. ; Vosmerikov, A. V. ; Prosvirin, I. P. ; Zaikovskii, V. I. ; Uimin, M. A. ; Maikov, V. V. ; Lisovaya, K. N. ; Fedushchak, T. A. / Influence of Conditions of Cryogenic Molybdenite Grinding on the Activity of Bulk Sulfide Hydrotreating Catalysts. In: Petroleum Chemistry. 2020 ; Vol. 60, No. 3. pp. 365-372.

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title = "Influence of Conditions of Cryogenic Molybdenite Grinding on the Activity of Bulk Sulfide Hydrotreating Catalysts",

abstract = "Abstract: The milling of molybdenite under cryogenic conditions in argon has been performed for the first time, and the physicochemical properties of its samples, their catalytic activity in model reactions of hydrodesulfurization of dibenzothiophene and diesel components, and the ability to initiate the isopropylbenzene oxidation reaction have been studied. The samples have been found to exhibit high catalytic activity.",

keywords = "bulk sulfide catalysts, cryogenic dispersion, model hydrodesulfurization and oxidation reactions, molybdenite",

author = "Mikubaeva, {E. V.} and Akimov, {A. S.} and Zhuravkov, {S. P.} and Sizova, {N. V.} and Vosmerikov, {A. V.} and Prosvirin, {I. P.} and Zaikovskii, {V. I.} and Uimin, {M. A.} and Maikov, {V. V.} and Lisovaya, {K. N.} and Fedushchak, {T. A.}",

note = "Funding Information: This work was supported by the Ministry of Science and Higher Education of the Russian Federation as part of the state assignment of the Institute of Petroleum Chemistry of the Siberian Branch of the Russian Academy of Sciences, project no. V.46.2.1. Publisher Copyright: {\textcopyright} 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

year = "2020",

month = mar,

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doi = "10.1134/S0965544120030147",

language = "English",

volume = "60",

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T1 - Influence of Conditions of Cryogenic Molybdenite Grinding on the Activity of Bulk Sulfide Hydrotreating Catalysts

AU - Mikubaeva, E. V.

AU - Akimov, A. S.

AU - Zhuravkov, S. P.

AU - Sizova, N. V.

AU - Vosmerikov, A. V.

AU - Prosvirin, I. P.

AU - Zaikovskii, V. I.

AU - Uimin, M. A.

AU - Maikov, V. V.

AU - Lisovaya, K. N.

AU - Fedushchak, T. A.

N1 - Funding Information: This work was supported by the Ministry of Science and Higher Education of the Russian Federation as part of the state assignment of the Institute of Petroleum Chemistry of the Siberian Branch of the Russian Academy of Sciences, project no. V.46.2.1. Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/3/1

Y1 - 2020/3/1

N2 - Abstract: The milling of molybdenite under cryogenic conditions in argon has been performed for the first time, and the physicochemical properties of its samples, their catalytic activity in model reactions of hydrodesulfurization of dibenzothiophene and diesel components, and the ability to initiate the isopropylbenzene oxidation reaction have been studied. The samples have been found to exhibit high catalytic activity.

AB - Abstract: The milling of molybdenite under cryogenic conditions in argon has been performed for the first time, and the physicochemical properties of its samples, their catalytic activity in model reactions of hydrodesulfurization of dibenzothiophene and diesel components, and the ability to initiate the isopropylbenzene oxidation reaction have been studied. The samples have been found to exhibit high catalytic activity.

KW - bulk sulfide catalysts

KW - cryogenic dispersion

KW - model hydrodesulfurization and oxidation reactions

KW - molybdenite

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