Abstract
A study has been made of the spectra of electron paramagnetic resonance and of experimental curves of accumulation of free radicals in polytetrafluoroethylene at different temperatures and radiation doses. It has been found that at a temperature of 60oC, the curve of accumulation of stabilized radicals goes through the maximum and thereafter drops exponentially. The change in the parameters of intermolecular interaction causes the transformation of a standardly shaped accumulation curve with saturation to a nonmonotonic curve with a maximum.
| Original language | English |
|---|---|
| Pages (from-to) | 455-458 |
| Number of pages | 4 |
| Journal | Journal of Engineering Physics and Thermophysics |
| Volume | 85 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 1 Mar 2012 |
| Externally published | Yes |
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Keywords
- γ irradiation
- Phase state
- Polymer
- Structure
ASJC Scopus subject areas
- Condensed Matter Physics
- Engineering(all)
Cite this
Influence of γ irradiation on the conformation of free radicals in polytetrafluoroethylene. / Komarov, F. F.; Kupchishin, A. I.; Pivovarov, S. P.; Tlebaev, K. B.; Kusainov, A. T.; Rukhin, A. B.; Pozdeeva, T. V.
In: Journal of Engineering Physics and Thermophysics, Vol. 85, No. 2, 01.03.2012, p. 455-458.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Influence of γ irradiation on the conformation of free radicals in polytetrafluoroethylene
AU - Komarov, F. F.
AU - Kupchishin, A. I.
AU - Pivovarov, S. P.
AU - Tlebaev, K. B.
AU - Kusainov, A. T.
AU - Rukhin, A. B.
AU - Pozdeeva, T. V.
PY - 2012/3/1
Y1 - 2012/3/1
N2 - A study has been made of the spectra of electron paramagnetic resonance and of experimental curves of accumulation of free radicals in polytetrafluoroethylene at different temperatures and radiation doses. It has been found that at a temperature of 60oC, the curve of accumulation of stabilized radicals goes through the maximum and thereafter drops exponentially. The change in the parameters of intermolecular interaction causes the transformation of a standardly shaped accumulation curve with saturation to a nonmonotonic curve with a maximum.
AB - A study has been made of the spectra of electron paramagnetic resonance and of experimental curves of accumulation of free radicals in polytetrafluoroethylene at different temperatures and radiation doses. It has been found that at a temperature of 60oC, the curve of accumulation of stabilized radicals goes through the maximum and thereafter drops exponentially. The change in the parameters of intermolecular interaction causes the transformation of a standardly shaped accumulation curve with saturation to a nonmonotonic curve with a maximum.
KW - γ irradiation
KW - Phase state
KW - Polymer
KW - Structure
UR - http://www.scopus.com/inward/record.url?scp=84863657958&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84863657958&partnerID=8YFLogxK
U2 - 10.1007/s10891-012-0672-3
DO - 10.1007/s10891-012-0672-3
M3 - Article
VL - 85
SP - 455
EP - 458
JO - Journal of Engineering Physics and Thermophysics
JF - Journal of Engineering Physics and Thermophysics
SN - 1062-0125
IS - 2
ER -