Imido transfer of sulfonylimino-λ3-bromane makes possible the synthesis of sulfonylimino-λ3-iodanes

Masahito Ochiai, Aiko Nakano, Akira Yoshimura, Kazunori Miyamoto, Satoko Hayashi, Waro Nakanishi

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Sulfonylimino-λ3-bromane functions as a reactive nitrenoid, because of the hyperleaving group ability of aryl- λ3-bromanyl groups, and undergoes transimidations to iodobenzenes at room temperature under metal-free conditions probably via an SN2-type nitrenoid transition state, yielding sulfonylimino- λ3-iodanes.

Original languageEnglish
Pages (from-to)959-961
Number of pages3
JournalChemical Communications
Issue number8
DOIs
Publication statusPublished - 9 Mar 2009
Externally publishedYes

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Iodobenzenes
Metals
Temperature

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Imido transfer of sulfonylimino-λ3-bromane makes possible the synthesis of sulfonylimino-λ3-iodanes. / Ochiai, Masahito; Nakano, Aiko; Yoshimura, Akira; Miyamoto, Kazunori; Hayashi, Satoko; Nakanishi, Waro.

In: Chemical Communications, No. 8, 09.03.2009, p. 959-961.

Research output: Contribution to journalArticle

Ochiai, Masahito ; Nakano, Aiko ; Yoshimura, Akira ; Miyamoto, Kazunori ; Hayashi, Satoko ; Nakanishi, Waro. / Imido transfer of sulfonylimino-λ3-bromane makes possible the synthesis of sulfonylimino-λ3-iodanes. In: Chemical Communications. 2009 ; No. 8. pp. 959-961.
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