Imido transfer of sulfonylimino-λ3-bromane makes possible the synthesis of sulfonylimino-λ3-iodanes

Masahito Ochiai, Aiko Nakano, Akira Yoshimura, Kazunori Miyamoto, Satoko Hayashi, Waro Nakanishi

Research output: Contribution to journal › Article

14 Citations (Scopus)

Abstract

Sulfonylimino-λ3-bromane functions as a reactive nitrenoid, because of the hyperleaving group ability of aryl- λ3-bromanyl groups, and undergoes transimidations to iodobenzenes at room temperature under metal-free conditions probably via an SN2-type nitrenoid transition state, yielding sulfonylimino- λ3-iodanes.

Original languageEnglish
Pages (from-to)959-961
Number of pages3
JournalChemical Communications
Issue number8
DOIs
Publication statusPublished - 9 Mar 2009
Externally publishedYes

Fingerprint

Iodobenzenes
Metals
Temperature

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Imido transfer of sulfonylimino-λ3-bromane makes possible the synthesis of sulfonylimino-λ3-iodanes. / Ochiai, Masahito; Nakano, Aiko; Yoshimura, Akira; Miyamoto, Kazunori; Hayashi, Satoko; Nakanishi, Waro.

In: Chemical Communications, No. 8, 09.03.2009, p. 959-961.

Research output: Contribution to journal › Article

Ochiai, M, Nakano, A, Yoshimura, A, Miyamoto, K, Hayashi, S & Nakanishi, W 2009, 'Imido transfer of sulfonylimino-λ3-bromane makes possible the synthesis of sulfonylimino-λ3-iodanes', Chemical Communications, no. 8, pp. 959-961. https://doi.org/10.1039/b818489e
Ochiai M, Nakano A, Yoshimura A, Miyamoto K, Hayashi S, Nakanishi W. Imido transfer of sulfonylimino-λ3-bromane makes possible the synthesis of sulfonylimino-λ3-iodanes. Chemical Communications. 2009 Mar 9;(8):959-961. https://doi.org/10.1039/b818489e
Ochiai, Masahito ; Nakano, Aiko ; Yoshimura, Akira ; Miyamoto, Kazunori ; Hayashi, Satoko ; Nakanishi, Waro. / Imido transfer of sulfonylimino-λ3-bromane makes possible the synthesis of sulfonylimino-λ3-iodanes. In: Chemical Communications. 2009 ; No. 8. pp. 959-961.
@article{7cdb53216cb54055aba54a5a877e20a9,
title = "Imido transfer of sulfonylimino-λ3-bromane makes possible the synthesis of sulfonylimino-λ3-iodanes",
abstract = "Sulfonylimino-λ3-bromane functions as a reactive nitrenoid, because of the hyperleaving group ability of aryl- λ3-bromanyl groups, and undergoes transimidations to iodobenzenes at room temperature under metal-free conditions probably via an SN2-type nitrenoid transition state, yielding sulfonylimino- λ3-iodanes.",
author = "Masahito Ochiai and Aiko Nakano and Akira Yoshimura and Kazunori Miyamoto and Satoko Hayashi and Waro Nakanishi",
year = "2009",
month = "3",
day = "9",
doi = "10.1039/b818489e",
language = "English",
pages = "959--961",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "8",

}

TY - JOUR

T1 - Imido transfer of sulfonylimino-λ3-bromane makes possible the synthesis of sulfonylimino-λ3-iodanes

AU - Ochiai, Masahito

AU - Nakano, Aiko

AU - Yoshimura, Akira

AU - Miyamoto, Kazunori

AU - Hayashi, Satoko

AU - Nakanishi, Waro

PY - 2009/3/9

Y1 - 2009/3/9

N2 - Sulfonylimino-λ3-bromane functions as a reactive nitrenoid, because of the hyperleaving group ability of aryl- λ3-bromanyl groups, and undergoes transimidations to iodobenzenes at room temperature under metal-free conditions probably via an SN2-type nitrenoid transition state, yielding sulfonylimino- λ3-iodanes.

AB - Sulfonylimino-λ3-bromane functions as a reactive nitrenoid, because of the hyperleaving group ability of aryl- λ3-bromanyl groups, and undergoes transimidations to iodobenzenes at room temperature under metal-free conditions probably via an SN2-type nitrenoid transition state, yielding sulfonylimino- λ3-iodanes.

UR - http://www.scopus.com/inward/record.url?scp=61449108108&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=61449108108&partnerID=8YFLogxK

U2 - 10.1039/b818489e

DO - 10.1039/b818489e

M3 - Article

C2 - 19214329

AN - SCOPUS:61449108108

SP - 959

EP - 961

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 8

ER -

Access to Document