Imido transfer of sulfonylimino-λ3-bromane makes possible the synthesis of sulfonylimino-λ3-iodanes

Masahito Ochiai, Aiko Nakano, Akira Yoshimura, Kazunori Miyamoto, Satoko Hayashi, Waro Nakanishi

Research output: Contribution to journal › Article

Abstract

Sulfonylimino-λ³-bromane functions as a reactive nitrenoid, because of the hyperleaving group ability of aryl- λ³-bromanyl groups, and undergoes transimidations to iodobenzenes at room temperature under metal-free conditions probably via an S_N2-type nitrenoid transition state, yielding sulfonylimino- λ³-iodanes.

Original language	English
Pages (from-to)	959-961
Number of pages	3
Journal	Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/b818489e
Publication status	Published - 9 Mar 2009
Externally published	Yes

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ASJC Scopus subject areas

Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Catalysis
Chemistry(all)

Cite this

Ochiai, M., Nakano, A., Yoshimura, A., Miyamoto, K., Hayashi, S., & Nakanishi, W. (2009). Imido transfer of sulfonylimino-λ3-bromane makes possible the synthesis of sulfonylimino-λ3-iodanes. Chemical Communications, (8), 959-961. https://doi.org/10.1039/b818489e

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AU - Miyamoto, Kazunori

AU - Hayashi, Satoko

AU - Nakanishi, Waro

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AB - Sulfonylimino-λ3-bromane functions as a reactive nitrenoid, because of the hyperleaving group ability of aryl- λ3-bromanyl groups, and undergoes transimidations to iodobenzenes at room temperature under metal-free conditions probably via an SN2-type nitrenoid transition state, yielding sulfonylimino- λ3-iodanes.

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Access to Document

10.1039/b818489e