Imido transfer of sulfonylimino-λ3-bromane makes possible the synthesis of sulfonylimino-λ3-iodanes

Masahito Ochiai, Aiko Nakano, Akira Yoshimura, Kazunori Miyamoto, Satoko Hayashi, Waro Nakanishi

Research output: Contribution to journal › Article › peer-review

Abstract

Sulfonylimino-λ³-bromane functions as a reactive nitrenoid, because of the hyperleaving group ability of aryl- λ³-bromanyl groups, and undergoes transimidations to iodobenzenes at room temperature under metal-free conditions probably via an S_N2-type nitrenoid transition state, yielding sulfonylimino- λ³-iodanes.

Original language	English
Pages (from-to)	959-961
Number of pages	3
Journal	Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/b818489e
Publication status	Published - 9 Mar 2009
Externally published	Yes

ASJC Scopus subject areas

Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Catalysis
Chemistry(all)

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abstract = "Sulfonylimino-λ3-bromane functions as a reactive nitrenoid, because of the hyperleaving group ability of aryl- λ3-bromanyl groups, and undergoes transimidations to iodobenzenes at room temperature under metal-free conditions probably via an SN2-type nitrenoid transition state, yielding sulfonylimino- λ3-iodanes.",

author = "Masahito Ochiai and Aiko Nakano and Akira Yoshimura and Kazunori Miyamoto and Satoko Hayashi and Waro Nakanishi",

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AU - Ochiai, Masahito

AU - Nakano, Aiko

AU - Yoshimura, Akira

AU - Miyamoto, Kazunori

AU - Hayashi, Satoko

AU - Nakanishi, Waro

PY - 2009/3/9

Y1 - 2009/3/9

N2 - Sulfonylimino-λ3-bromane functions as a reactive nitrenoid, because of the hyperleaving group ability of aryl- λ3-bromanyl groups, and undergoes transimidations to iodobenzenes at room temperature under metal-free conditions probably via an SN2-type nitrenoid transition state, yielding sulfonylimino- λ3-iodanes.

AB - Sulfonylimino-λ3-bromane functions as a reactive nitrenoid, because of the hyperleaving group ability of aryl- λ3-bromanyl groups, and undergoes transimidations to iodobenzenes at room temperature under metal-free conditions probably via an SN2-type nitrenoid transition state, yielding sulfonylimino- λ3-iodanes.

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Imido transfer of sulfonylimino-λ3-bromane makes possible the synthesis of sulfonylimino-λ3-iodanes

Abstract

ASJC Scopus subject areas

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