Abstract
Sulfonylimino-λ3-bromane functions as a reactive nitrenoid, because of the hyperleaving group ability of aryl- λ3-bromanyl groups, and undergoes transimidations to iodobenzenes at room temperature under metal-free conditions probably via an SN2-type nitrenoid transition state, yielding sulfonylimino- λ3-iodanes.
Original language | English |
---|---|
Pages (from-to) | 959-961 |
Number of pages | 3 |
Journal | Chemical Communications |
Issue number | 8 |
DOIs | |
Publication status | Published - 9 Mar 2009 |
Externally published | Yes |
Fingerprint
ASJC Scopus subject areas
- Metals and Alloys
- Materials Chemistry
- Surfaces, Coatings and Films
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Catalysis
- Chemistry(all)
Cite this
Imido transfer of sulfonylimino-λ3-bromane makes possible the synthesis of sulfonylimino-λ3-iodanes. / Ochiai, Masahito; Nakano, Aiko; Yoshimura, Akira; Miyamoto, Kazunori; Hayashi, Satoko; Nakanishi, Waro.
In: Chemical Communications, No. 8, 09.03.2009, p. 959-961.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Imido transfer of sulfonylimino-λ3-bromane makes possible the synthesis of sulfonylimino-λ3-iodanes
AU - Ochiai, Masahito
AU - Nakano, Aiko
AU - Yoshimura, Akira
AU - Miyamoto, Kazunori
AU - Hayashi, Satoko
AU - Nakanishi, Waro
PY - 2009/3/9
Y1 - 2009/3/9
N2 - Sulfonylimino-λ3-bromane functions as a reactive nitrenoid, because of the hyperleaving group ability of aryl- λ3-bromanyl groups, and undergoes transimidations to iodobenzenes at room temperature under metal-free conditions probably via an SN2-type nitrenoid transition state, yielding sulfonylimino- λ3-iodanes.
AB - Sulfonylimino-λ3-bromane functions as a reactive nitrenoid, because of the hyperleaving group ability of aryl- λ3-bromanyl groups, and undergoes transimidations to iodobenzenes at room temperature under metal-free conditions probably via an SN2-type nitrenoid transition state, yielding sulfonylimino- λ3-iodanes.
UR - http://www.scopus.com/inward/record.url?scp=61449108108&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=61449108108&partnerID=8YFLogxK
U2 - 10.1039/b818489e
DO - 10.1039/b818489e
M3 - Article
C2 - 19214329
AN - SCOPUS:61449108108
SP - 959
EP - 961
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 8
ER -