Ignition study of high-energy materials containing Al, B, AlB2 and TiB2 powders

Abstract

Boron and its compounds are considered as possible high efficiency fuel components for high-energy materials (HEMs), since they have high gravimetric and volumetric heats of oxidation in comparison with aluminium powder. This work aims to modify a commercial 99.5% pure boron and AlB₂ or TiB₂ powders to improve the ignition and combustion characteristics for solid propellants. The ignition parameters for the model HEM sample based on ammonium perchlorate, ammonium nitrate and energetic binder, containing Al, B, AlB₂ and TiB₂ powders are presented. It was found that the greatest effect at the laser ignition is achieved at a full replacement of Al by B powder, at which the ignition time and the activation energy of HEM are reduced by 2.1-2.7 and 1.8 times, respectively. When replacing Al by AlB₂ powder in HEM the ignition time is reduced by 1.7-2.4 times, and the activation energy is increased by 1.4 times.

Original language	English
Article number	03016
Journal	MATEC Web of Conferences
Volume	115
DOIs	https://doi.org/10.1051/matecconf/201711503016
Publication status	Published - 10 Jul 2017
Event	33rd Siberian Thermophysical Seminar, STS 2017 - Novosibirsk, Russian Federation Duration: 6 Jun 2017 → 8 Jun 2017

ASJC Scopus subject areas

Chemistry(all)
Engineering(all)
Materials Science(all)

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10.1051/matecconf/201711503016

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title = "Ignition study of high-energy materials containing Al, B, AlB2 and TiB2 powders",

abstract = "Boron and its compounds are considered as possible high efficiency fuel components for high-energy materials (HEMs), since they have high gravimetric and volumetric heats of oxidation in comparison with aluminium powder. This work aims to modify a commercial 99.5% pure boron and AlB2 or TiB2 powders to improve the ignition and combustion characteristics for solid propellants. The ignition parameters for the model HEM sample based on ammonium perchlorate, ammonium nitrate and energetic binder, containing Al, B, AlB2 and TiB2 powders are presented. It was found that the greatest effect at the laser ignition is achieved at a full replacement of Al by B powder, at which the ignition time and the activation energy of HEM are reduced by 2.1-2.7 and 1.8 times, respectively. When replacing Al by AlB2 powder in HEM the ignition time is reduced by 1.7-2.4 times, and the activation energy is increased by 1.4 times.",

author = "Alexander Korotkikh and Vladimir Arkhipov and Konstantin Slyusarskiy and Ivan Sorokin",

year = "2017",

month = jul,

day = "10",

doi = "10.1051/matecconf/201711503016",

language = "English",

volume = "115",

journal = "MATEC Web of Conferences",

note = "33rd Siberian Thermophysical Seminar, STS 2017 ; Conference date: 06-06-2017 Through 08-06-2017",

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TY - JOUR

T1 - Ignition study of high-energy materials containing Al, B, AlB2 and TiB2 powders

AU - Korotkikh, Alexander

AU - Arkhipov, Vladimir

AU - Slyusarskiy, Konstantin

AU - Sorokin, Ivan

PY - 2017/7/10

Y1 - 2017/7/10

N2 - Boron and its compounds are considered as possible high efficiency fuel components for high-energy materials (HEMs), since they have high gravimetric and volumetric heats of oxidation in comparison with aluminium powder. This work aims to modify a commercial 99.5% pure boron and AlB2 or TiB2 powders to improve the ignition and combustion characteristics for solid propellants. The ignition parameters for the model HEM sample based on ammonium perchlorate, ammonium nitrate and energetic binder, containing Al, B, AlB2 and TiB2 powders are presented. It was found that the greatest effect at the laser ignition is achieved at a full replacement of Al by B powder, at which the ignition time and the activation energy of HEM are reduced by 2.1-2.7 and 1.8 times, respectively. When replacing Al by AlB2 powder in HEM the ignition time is reduced by 1.7-2.4 times, and the activation energy is increased by 1.4 times.

AB - Boron and its compounds are considered as possible high efficiency fuel components for high-energy materials (HEMs), since they have high gravimetric and volumetric heats of oxidation in comparison with aluminium powder. This work aims to modify a commercial 99.5% pure boron and AlB2 or TiB2 powders to improve the ignition and combustion characteristics for solid propellants. The ignition parameters for the model HEM sample based on ammonium perchlorate, ammonium nitrate and energetic binder, containing Al, B, AlB2 and TiB2 powders are presented. It was found that the greatest effect at the laser ignition is achieved at a full replacement of Al by B powder, at which the ignition time and the activation energy of HEM are reduced by 2.1-2.7 and 1.8 times, respectively. When replacing Al by AlB2 powder in HEM the ignition time is reduced by 1.7-2.4 times, and the activation energy is increased by 1.4 times.

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Y2 - 6 June 2017 through 8 June 2017

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Ignition study of high-energy materials containing Al, B, AlB₂ and TiB₂ powders

Abstract

ASJC Scopus subject areas

Access to Document

Fingerprint Dive into the research topics of 'Ignition study of high-energy materials containing Al, B, AlB<sub>2</sub> and TiB<sub>2</sub> powders'. Together they form a unique fingerprint.

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