Hypervalent iodine in the structure of N-heterocycles: synthesis, structure, and application in organic synthesis

Abstract

[Figure not available: see fulltext.] The review is devoted to one of the most substantial trends in the chemistry of hypervalent iodine – synthesis, structure, and properties of heterocyclic and pseudoheterocyclic systems based on λ³- and λ⁵-iodanes. Among the variety of cyclic reagents based on hypervalent iodine, special attention has recently been paid to iodanes having close contact between I and N atoms. The review is addressing the synthetic approaches, structural features, and application of these reagents. The review includes more than 100 literature sources, mainly covering publications from 1990 to 2020 and key research from earlier years.

Original language	English
Journal	Chemistry of Heterocyclic Compounds
DOIs	https://doi.org/10.1007/s10593-020-02742-0
Publication status	Accepted/In press - 2020

Keywords

hypervalent iodine
nitrogen–iodine bond
organoiodine compounds
oxidation
pseudoheterocyclic compounds

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1007/s10593-020-02742-0

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title = "Hypervalent iodine in the structure of N-heterocycles: synthesis, structure, and application in organic synthesis",

abstract = "[Figure not available: see fulltext.] The review is devoted to one of the most substantial trends in the chemistry of hypervalent iodine – synthesis, structure, and properties of heterocyclic and pseudoheterocyclic systems based on λ3- and λ5-iodanes. Among the variety of cyclic reagents based on hypervalent iodine, special attention has recently been paid to iodanes having close contact between I and N atoms. The review is addressing the synthetic approaches, structural features, and application of these reagents. The review includes more than 100 literature sources, mainly covering publications from 1990 to 2020 and key research from earlier years.",

keywords = "hypervalent iodine, nitrogen–iodine bond, organoiodine compounds, oxidation, pseudoheterocyclic compounds",

author = "Yulia Vlasenko and Yusubov, {Mekhman S.} and Alexandr Shafir and Postnikov, {Pavel S.}",

year = "2020",

doi = "10.1007/s10593-020-02742-0",

language = "English",

journal = "Chemistry of Heterocyclic Compounds",

issn = "0009-3122",

publisher = "Springer New York",

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T1 - Hypervalent iodine in the structure of N-heterocycles

T2 - synthesis, structure, and application in organic synthesis

AU - Vlasenko, Yulia

AU - Yusubov, Mekhman S.

AU - Shafir, Alexandr

AU - Postnikov, Pavel S.

PY - 2020

Y1 - 2020

N2 - [Figure not available: see fulltext.] The review is devoted to one of the most substantial trends in the chemistry of hypervalent iodine – synthesis, structure, and properties of heterocyclic and pseudoheterocyclic systems based on λ3- and λ5-iodanes. Among the variety of cyclic reagents based on hypervalent iodine, special attention has recently been paid to iodanes having close contact between I and N atoms. The review is addressing the synthetic approaches, structural features, and application of these reagents. The review includes more than 100 literature sources, mainly covering publications from 1990 to 2020 and key research from earlier years.

AB - [Figure not available: see fulltext.] The review is devoted to one of the most substantial trends in the chemistry of hypervalent iodine – synthesis, structure, and properties of heterocyclic and pseudoheterocyclic systems based on λ3- and λ5-iodanes. Among the variety of cyclic reagents based on hypervalent iodine, special attention has recently been paid to iodanes having close contact between I and N atoms. The review is addressing the synthetic approaches, structural features, and application of these reagents. The review includes more than 100 literature sources, mainly covering publications from 1990 to 2020 and key research from earlier years.

KW - hypervalent iodine

KW - nitrogen–iodine bond

KW - organoiodine compounds

KW - oxidation

KW - pseudoheterocyclic compounds

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