TY - JOUR
T1 - Hypervalent iodine in the structure of N-heterocycles
T2 - synthesis, structure, and application in organic synthesis
AU - Vlasenko, Yulia
AU - Yusubov, Mekhman S.
AU - Shafir, Alexandr
AU - Postnikov, Pavel S.
PY - 2020
Y1 - 2020
N2 - [Figure not available: see fulltext.] The review is devoted to one of the most substantial trends in the chemistry of hypervalent iodine – synthesis, structure, and properties of heterocyclic and pseudoheterocyclic systems based on λ3- and λ5-iodanes. Among the variety of cyclic reagents based on hypervalent iodine, special attention has recently been paid to iodanes having close contact between I and N atoms. The review is addressing the synthetic approaches, structural features, and application of these reagents. The review includes more than 100 literature sources, mainly covering publications from 1990 to 2020 and key research from earlier years.
AB - [Figure not available: see fulltext.] The review is devoted to one of the most substantial trends in the chemistry of hypervalent iodine – synthesis, structure, and properties of heterocyclic and pseudoheterocyclic systems based on λ3- and λ5-iodanes. Among the variety of cyclic reagents based on hypervalent iodine, special attention has recently been paid to iodanes having close contact between I and N atoms. The review is addressing the synthetic approaches, structural features, and application of these reagents. The review includes more than 100 literature sources, mainly covering publications from 1990 to 2020 and key research from earlier years.
KW - hypervalent iodine
KW - nitrogen–iodine bond
KW - organoiodine compounds
KW - oxidation
KW - pseudoheterocyclic compounds
UR - http://www.scopus.com/inward/record.url?scp=85089729036&partnerID=8YFLogxK
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U2 - 10.1007/s10593-020-02742-0
DO - 10.1007/s10593-020-02742-0
M3 - Article
AN - SCOPUS:85089729036
JO - Chemistry of Heterocyclic Compounds
JF - Chemistry of Heterocyclic Compounds
SN - 0009-3122
ER -