Hydroxyapatite coating on biodegradable AZ31 and Mg-Ca alloys prepared by RF-magnetron sputtering

T. Mukhametkaliyev, M. Surmeneva, R. Surmenev, B. K. Mathan

Research Center for Physical Materials Science and Composite Materials

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

A thin film of hydroxyapatite (HA) was deposited on AZ31 and Mg-Ca alloys by using radio frequency (RF) magnetron sputtering. The thickness of the HA coating was determined to be 750 nm. The phase composition, microstructure, and surface morphology of the HA coatings were investigated using X-ray diffraction and scanning electron microscopy. In vitro degradation behaviour of the HA coated alloys was evaluated in simulated body fluid (SBF) and 3.5wt.% NaCl solution using electrochemical method. The coatings homogeneously covered the entire surface of the substrates. The coating structure corresponded to a nanostructured HA. The ultrathin coating significantly improved the degradation resistance of the alloy. Nanocrystalline HA coating significantly improved the corrosion resistance of the Mg-Ca and AZ31 magnesium alloys. The polarization resistance (Rp) of the coated Mg-Ca alloy was more than two-order of magnitude higher and the corrosion current density I_corr reduced by ∼ 98% as compared to the base alloy.

Original language	English
Title of host publication	New Operational Technologies, NEWOT 2015: Proceedings of the 5th International Scientific Conference "New Operational Technologies"
Publisher	American Institute of Physics Inc.
Volume	1688
ISBN (Electronic)	9780735413351
DOIs	https://doi.org/10.1063/1.4936001
Publication status	Published - 17 Nov 2015
Event	5th International Scientific Conference on New Operational Technologies, NEWOT 2015 - Tomsk, Russian Federation Duration: 29 Sep 2015 → 30 Sep 2015

Conference

Conference	5th International Scientific Conference on New Operational Technologies, NEWOT 2015
Country	Russian Federation
City	Tomsk
Period	29.9.15 → 30.9.15

Fingerprint

ASJC Scopus subject areas

Physics and Astronomy(all)

Cite this

Mukhametkaliyev, T., Surmeneva, M., Surmenev, R., & Mathan, B. K. (2015). Hydroxyapatite coating on biodegradable AZ31 and Mg-Ca alloys prepared by RF-magnetron sputtering. In New Operational Technologies, NEWOT 2015: Proceedings of the 5th International Scientific Conference "New Operational Technologies" (Vol. 1688). [030006] American Institute of Physics Inc.. https://doi.org/10.1063/1.4936001

Hydroxyapatite coating on biodegradable AZ31 and Mg-Ca alloys prepared by RF-magnetron sputtering. / Mukhametkaliyev, T.; Surmeneva, M.; Surmenev, R.; Mathan, B. K.

New Operational Technologies, NEWOT 2015: Proceedings of the 5th International Scientific Conference "New Operational Technologies". Vol. 1688 American Institute of Physics Inc., 2015. 030006.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Mukhametkaliyev, T, Surmeneva, M , Surmenev, R & Mathan, BK 2015, Hydroxyapatite coating on biodegradable AZ31 and Mg-Ca alloys prepared by RF-magnetron sputtering. in New Operational Technologies, NEWOT 2015: Proceedings of the 5th International Scientific Conference "New Operational Technologies". vol. 1688, 030006, American Institute of Physics Inc., 5th International Scientific Conference on New Operational Technologies, NEWOT 2015, Tomsk, Russian Federation, 29.9.15. https://doi.org/10.1063/1.4936001

Mukhametkaliyev T, Surmeneva M , Surmenev R, Mathan BK. Hydroxyapatite coating on biodegradable AZ31 and Mg-Ca alloys prepared by RF-magnetron sputtering. In New Operational Technologies, NEWOT 2015: Proceedings of the 5th International Scientific Conference "New Operational Technologies". Vol. 1688. American Institute of Physics Inc. 2015. 030006 https://doi.org/10.1063/1.4936001

@inproceedings{3c0a67d4200e429e875b4d01dc011d88,

title = "Hydroxyapatite coating on biodegradable AZ31 and Mg-Ca alloys prepared by RF-magnetron sputtering",

abstract = "A thin film of hydroxyapatite (HA) was deposited on AZ31 and Mg-Ca alloys by using radio frequency (RF) magnetron sputtering. The thickness of the HA coating was determined to be 750 nm. The phase composition, microstructure, and surface morphology of the HA coatings were investigated using X-ray diffraction and scanning electron microscopy. In vitro degradation behaviour of the HA coated alloys was evaluated in simulated body fluid (SBF) and 3.5wt.{\%} NaCl solution using electrochemical method. The coatings homogeneously covered the entire surface of the substrates. The coating structure corresponded to a nanostructured HA. The ultrathin coating significantly improved the degradation resistance of the alloy. Nanocrystalline HA coating significantly improved the corrosion resistance of the Mg-Ca and AZ31 magnesium alloys. The polarization resistance (Rp) of the coated Mg-Ca alloy was more than two-order of magnitude higher and the corrosion current density Icorr reduced by ∼ 98{\%} as compared to the base alloy.",

author = "T. Mukhametkaliyev and M. Surmeneva and R. Surmenev and Mathan, {B. K.}",

year = "2015",

month = "11",

day = "17",

doi = "10.1063/1.4936001",

language = "English",

volume = "1688",

booktitle = "New Operational Technologies, NEWOT 2015: Proceedings of the 5th International Scientific Conference {"}New Operational Technologies{"}",

publisher = "American Institute of Physics Inc.",

note = "5th International Scientific Conference on New Operational Technologies, NEWOT 2015 ; Conference date: 29-09-2015 Through 30-09-2015",

}

TY - GEN

T1 - Hydroxyapatite coating on biodegradable AZ31 and Mg-Ca alloys prepared by RF-magnetron sputtering

AU - Mukhametkaliyev, T.

AU - Surmeneva, M.

AU - Surmenev, R.

AU - Mathan, B. K.

PY - 2015/11/17

Y1 - 2015/11/17

N2 - A thin film of hydroxyapatite (HA) was deposited on AZ31 and Mg-Ca alloys by using radio frequency (RF) magnetron sputtering. The thickness of the HA coating was determined to be 750 nm. The phase composition, microstructure, and surface morphology of the HA coatings were investigated using X-ray diffraction and scanning electron microscopy. In vitro degradation behaviour of the HA coated alloys was evaluated in simulated body fluid (SBF) and 3.5wt.% NaCl solution using electrochemical method. The coatings homogeneously covered the entire surface of the substrates. The coating structure corresponded to a nanostructured HA. The ultrathin coating significantly improved the degradation resistance of the alloy. Nanocrystalline HA coating significantly improved the corrosion resistance of the Mg-Ca and AZ31 magnesium alloys. The polarization resistance (Rp) of the coated Mg-Ca alloy was more than two-order of magnitude higher and the corrosion current density Icorr reduced by ∼ 98% as compared to the base alloy.

AB - A thin film of hydroxyapatite (HA) was deposited on AZ31 and Mg-Ca alloys by using radio frequency (RF) magnetron sputtering. The thickness of the HA coating was determined to be 750 nm. The phase composition, microstructure, and surface morphology of the HA coatings were investigated using X-ray diffraction and scanning electron microscopy. In vitro degradation behaviour of the HA coated alloys was evaluated in simulated body fluid (SBF) and 3.5wt.% NaCl solution using electrochemical method. The coatings homogeneously covered the entire surface of the substrates. The coating structure corresponded to a nanostructured HA. The ultrathin coating significantly improved the degradation resistance of the alloy. Nanocrystalline HA coating significantly improved the corrosion resistance of the Mg-Ca and AZ31 magnesium alloys. The polarization resistance (Rp) of the coated Mg-Ca alloy was more than two-order of magnitude higher and the corrosion current density Icorr reduced by ∼ 98% as compared to the base alloy.

UR - http://www.scopus.com/inward/record.url?scp=84984548265&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84984548265&partnerID=8YFLogxK

U2 - 10.1063/1.4936001

DO - 10.1063/1.4936001

M3 - Conference contribution

AN - SCOPUS:84984548265

VL - 1688

BT - New Operational Technologies, NEWOT 2015: Proceedings of the 5th International Scientific Conference "New Operational Technologies"

PB - American Institute of Physics Inc.

T2 - 5th International Scientific Conference on New Operational Technologies, NEWOT 2015

Y2 - 29 September 2015 through 30 September 2015

ER -

Access to Document

10.1063/1.4936001