HPLC determination of naphthalene amino derivatives using electrochemical detection at carbon paste electrodes

Abstract

HPLC with electrochemical detection using a carbon paste electrode based on glassy carbon spherical microparticles with an organic pasting liquid has been used for the determination of trace amounts of carcinogenic 1-naphthylamine, 2-naphthylamine, 1,5-diaminonaphthalene and 1,8-diaminonaphthalene. The lowest limit of detection found was 5.4 × 10^-9 mol L^-1 for 1,5-diaminonaphthalene. The limits of detection for the above analytes using the electrochemical detection with a carbon paste electrode were in all cases lower than the corresponding limits of detection for the spectrophotometric detection. The newly developed method of determination was verified on model samples of drinking and river water.

Original language	English
Pages (from-to)	185-190
Number of pages	6
Journal	Electroanalysis
Volume	19
Issue number	2-3
DOIs	https://doi.org/10.1002/elan.200603690
Publication status	Published - 1 Jan 2007
Externally published	Yes

Keywords

Amino derivatives of polycyclic aromatic hydrocarbons
Glassy carbon paste electrode
HPLC with electrochemical detection

ASJC Scopus subject areas

Analytical Chemistry
Electrochemistry

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10.1002/elan.200603690

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title = "HPLC determination of naphthalene amino derivatives using electrochemical detection at carbon paste electrodes",

abstract = "HPLC with electrochemical detection using a carbon paste electrode based on glassy carbon spherical microparticles with an organic pasting liquid has been used for the determination of trace amounts of carcinogenic 1-naphthylamine, 2-naphthylamine, 1,5-diaminonaphthalene and 1,8-diaminonaphthalene. The lowest limit of detection found was 5.4 × 10-9 mol L-1 for 1,5-diaminonaphthalene. The limits of detection for the above analytes using the electrochemical detection with a carbon paste electrode were in all cases lower than the corresponding limits of detection for the spectrophotometric detection. The newly developed method of determination was verified on model samples of drinking and river water.",

keywords = "Amino derivatives of polycyclic aromatic hydrocarbons, Glassy carbon paste electrode, HPLC with electrochemical detection",

author = "Jiri Zima and Hana Dejmkova and Jiri Barek",

year = "2007",

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doi = "10.1002/elan.200603690",

language = "English",

volume = "19",

pages = "185--190",

journal = "Macromolecular Chemistry and Physics",

issn = "1040-0397",

publisher = "Wiley-VCH Verlag",

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}

TY - JOUR

T1 - HPLC determination of naphthalene amino derivatives using electrochemical detection at carbon paste electrodes

AU - Zima, Jiri

AU - Dejmkova, Hana

AU - Barek, Jiri

PY - 2007/1/1

Y1 - 2007/1/1

N2 - HPLC with electrochemical detection using a carbon paste electrode based on glassy carbon spherical microparticles with an organic pasting liquid has been used for the determination of trace amounts of carcinogenic 1-naphthylamine, 2-naphthylamine, 1,5-diaminonaphthalene and 1,8-diaminonaphthalene. The lowest limit of detection found was 5.4 × 10-9 mol L-1 for 1,5-diaminonaphthalene. The limits of detection for the above analytes using the electrochemical detection with a carbon paste electrode were in all cases lower than the corresponding limits of detection for the spectrophotometric detection. The newly developed method of determination was verified on model samples of drinking and river water.

AB - HPLC with electrochemical detection using a carbon paste electrode based on glassy carbon spherical microparticles with an organic pasting liquid has been used for the determination of trace amounts of carcinogenic 1-naphthylamine, 2-naphthylamine, 1,5-diaminonaphthalene and 1,8-diaminonaphthalene. The lowest limit of detection found was 5.4 × 10-9 mol L-1 for 1,5-diaminonaphthalene. The limits of detection for the above analytes using the electrochemical detection with a carbon paste electrode were in all cases lower than the corresponding limits of detection for the spectrophotometric detection. The newly developed method of determination was verified on model samples of drinking and river water.

KW - Amino derivatives of polycyclic aromatic hydrocarbons

KW - Glassy carbon paste electrode

KW - HPLC with electrochemical detection

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