High-resolution study of the (v₁ + 1/2v₂ + v₃ = 13) polyad of strongly interacting vibrational bands of d₂o

O. N. Ulenikov, Sheng Gui He, G. A. Onopenko, E. S. Bekhtereva, Xiang Huai Wang, Shui Ming Hu, Hai Lin, Qing Shi Zhu

Research School of High-Energy Physics

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Abstract

Analysis of the high-resolution Fourier transform spectra of the D₂O first decade was carried out in the framework of the Hamiltonian model which took into account resonance interactions between the seven states, (300), (201), (102), (003), (220), (121), and (022). Assigned from the experimentally recorded spectrum transitions belonged to the four bands, 2v₁ + v₃, 3v₃, v₁ + 2v₂ + v₃, and 3v₁, gave the possibility both of obtaining rotational, centrifugal distortion, and resonance interaction parameters of "appeared" states, (201), (003), (121), and (300), and of estimating from the fit band centers, rotational, and resonance interaction parameters of the three "dark" states, (220), (022), and (102).

Original language	English
Pages (from-to)	216-225
Number of pages	10
Journal	Journal of Molecular Spectroscopy
Volume	204
Issue number	2
DOIs	https://doi.org/10.1006/jmsp.2000.8221
Publication status	Published - 1 Jan 2000

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ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry

Cite this

Ulenikov, O. N., He, S. G., Onopenko, G. A., Bekhtereva, E. S., Wang, X. H., Hu, S. M., Lin, H., & Zhu, Q. S. (2000). High-resolution study of the (v₁ + 1/2v₂ + v₃ = 13) polyad of strongly interacting vibrational bands of d₂o. Journal of Molecular Spectroscopy, 204(2), 216-225. https://doi.org/10.1006/jmsp.2000.8221

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title = "High-resolution study of the (v1 + 1/2v2 + v3 = 13) polyad of strongly interacting vibrational bands of d2o",

abstract = "Analysis of the high-resolution Fourier transform spectra of the D2O first decade was carried out in the framework of the Hamiltonian model which took into account resonance interactions between the seven states, (300), (201), (102), (003), (220), (121), and (022). Assigned from the experimentally recorded spectrum transitions belonged to the four bands, 2v1 + v3, 3v3, v1 + 2v2 + v3, and 3v1, gave the possibility both of obtaining rotational, centrifugal distortion, and resonance interaction parameters of {"}appeared{"} states, (201), (003), (121), and (300), and of estimating from the fit band centers, rotational, and resonance interaction parameters of the three {"}dark{"} states, (220), (022), and (102).",

author = "Ulenikov, {O. N.} and He, {Sheng Gui} and Onopenko, {G. A.} and Bekhtereva, {E. S.} and Wang, {Xiang Huai} and Hu, {Shui Ming} and Hai Lin and Zhu, {Qing Shi}",

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T1 - High-resolution study of the (v1 + 1/2v2 + v3 = 13) polyad of strongly interacting vibrational bands of d2o

AU - Ulenikov, O. N.

AU - He, Sheng Gui

AU - Onopenko, G. A.

AU - Bekhtereva, E. S.

AU - Wang, Xiang Huai

AU - Hu, Shui Ming

AU - Lin, Hai

AU - Zhu, Qing Shi

PY - 2000/1/1

Y1 - 2000/1/1

N2 - Analysis of the high-resolution Fourier transform spectra of the D2O first decade was carried out in the framework of the Hamiltonian model which took into account resonance interactions between the seven states, (300), (201), (102), (003), (220), (121), and (022). Assigned from the experimentally recorded spectrum transitions belonged to the four bands, 2v1 + v3, 3v3, v1 + 2v2 + v3, and 3v1, gave the possibility both of obtaining rotational, centrifugal distortion, and resonance interaction parameters of "appeared" states, (201), (003), (121), and (300), and of estimating from the fit band centers, rotational, and resonance interaction parameters of the three "dark" states, (220), (022), and (102).

AB - Analysis of the high-resolution Fourier transform spectra of the D2O first decade was carried out in the framework of the Hamiltonian model which took into account resonance interactions between the seven states, (300), (201), (102), (003), (220), (121), and (022). Assigned from the experimentally recorded spectrum transitions belonged to the four bands, 2v1 + v3, 3v3, v1 + 2v2 + v3, and 3v1, gave the possibility both of obtaining rotational, centrifugal distortion, and resonance interaction parameters of "appeared" states, (201), (003), (121), and (300), and of estimating from the fit band centers, rotational, and resonance interaction parameters of the three "dark" states, (220), (022), and (102).

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10.1006/jmsp.2000.8221