Abstract
A high-resolution Fourier transform spectrum of the D2 MSe species (M = 82, 80, 78, 77, and 76) in the region 2300-2500 cm-1 was recorded for the first time and assigned. On the basis of these experimental data, rotation-vibration energies of the (1 1 0) and (0 1 1) vibrational states were fitted, and band centers, and rotational, centrifugal distortion, and resonance interaction parameters were determined for the main D2 80Se species. The obtained set of 32 fitted parameters reproduces the 647 rotation-vibration energies with a rms deviation of 0.00024 cm-1. The ν1 + ν2 and ν2 + ν3 bands of the other four isotopic species are analyzed as well.
| Original language | English |
|---|---|
| Pages (from-to) | 78-86 |
| Number of pages | 9 |
| Journal | Journal of Molecular Spectroscopy |
| Volume | 230 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1 Mar 2005 |
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Keywords
- Combinational bands
- DSe molecule
- Spectroscopic parameters
- Vibration-rotation spectra
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Spectroscopy
- Atomic and Molecular Physics, and Optics
Cite this
High-resolution study of the ν1 + ν2 and ν2 + ν3 strongly interacting bands of D 2Se. / Ulenikov, O. N.; Onopenko, G. A.; Krapivina, T. V.; Gromova, O. V.
In: Journal of Molecular Spectroscopy, Vol. 230, No. 1, 01.03.2005, p. 78-86.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - High-resolution study of the ν1 + ν2 and ν2 + ν3 strongly interacting bands of D 2Se
AU - Ulenikov, O. N.
AU - Onopenko, G. A.
AU - Krapivina, T. V.
AU - Gromova, O. V.
PY - 2005/3/1
Y1 - 2005/3/1
N2 - A high-resolution Fourier transform spectrum of the D2 MSe species (M = 82, 80, 78, 77, and 76) in the region 2300-2500 cm-1 was recorded for the first time and assigned. On the basis of these experimental data, rotation-vibration energies of the (1 1 0) and (0 1 1) vibrational states were fitted, and band centers, and rotational, centrifugal distortion, and resonance interaction parameters were determined for the main D2 80Se species. The obtained set of 32 fitted parameters reproduces the 647 rotation-vibration energies with a rms deviation of 0.00024 cm-1. The ν1 + ν2 and ν2 + ν3 bands of the other four isotopic species are analyzed as well.
AB - A high-resolution Fourier transform spectrum of the D2 MSe species (M = 82, 80, 78, 77, and 76) in the region 2300-2500 cm-1 was recorded for the first time and assigned. On the basis of these experimental data, rotation-vibration energies of the (1 1 0) and (0 1 1) vibrational states were fitted, and band centers, and rotational, centrifugal distortion, and resonance interaction parameters were determined for the main D2 80Se species. The obtained set of 32 fitted parameters reproduces the 647 rotation-vibration energies with a rms deviation of 0.00024 cm-1. The ν1 + ν2 and ν2 + ν3 bands of the other four isotopic species are analyzed as well.
KW - Combinational bands
KW - DSe molecule
KW - Spectroscopic parameters
KW - Vibration-rotation spectra
UR - http://www.scopus.com/inward/record.url?scp=13144275293&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=13144275293&partnerID=8YFLogxK
U2 - 10.1016/j.jms.2004.10.010
DO - 10.1016/j.jms.2004.10.010
M3 - Article
VL - 230
SP - 78
EP - 86
JO - Journal of Molecular Spectroscopy
JF - Journal of Molecular Spectroscopy
SN - 0022-2852
IS - 1
ER -