High-resolution study of the ν1 + ν2 and ν2 + ν3 strongly interacting bands of D 2Se

O. N. Ulenikov, G. A. Onopenko, T. V. Krapivina, O. V. Gromova

Research output: Contribution to journalArticle

Abstract

A high-resolution Fourier transform spectrum of the D2 MSe species (M = 82, 80, 78, 77, and 76) in the region 2300-2500 cm-1 was recorded for the first time and assigned. On the basis of these experimental data, rotation-vibration energies of the (1 1 0) and (0 1 1) vibrational states were fitted, and band centers, and rotational, centrifugal distortion, and resonance interaction parameters were determined for the main D2 80Se species. The obtained set of 32 fitted parameters reproduces the 647 rotation-vibration energies with a rms deviation of 0.00024 cm-1. The ν1 + ν2 and ν2 + ν3 bands of the other four isotopic species are analyzed as well.

Original languageEnglish
Pages (from-to)78-86
Number of pages9
JournalJournal of Molecular Spectroscopy
Volume230
Issue number1
DOIs
Publication statusPublished - 1 Mar 2005

Keywords

  • Combinational bands
  • DSe molecule
  • Spectroscopic parameters
  • Vibration-rotation spectra

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

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