High Resolution Study of Deuterated Hydrogen Sulfide in the Region 2400-3000 cm-1

O. N. Ulenikov, R. N. Tolchenov, E. N. Melekhina, M. Koivusaari, S. Alanko, R. Anttila

Research output: Contribution to journalArticle

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Abstract

High resolution Fourier transform spectra of deuterated hydrogen sulfide have been recorded in the region 2400-3000 cm-1. Rotational structures of the ν1 + ν2, ν2 + ν3 bands of D2 32S, of the ν3 and ν1 + ν2 bands of HD32S, and of the ν1 + ν2 band of HD34S were analyzed. Band centers and rotational, centrifugal distortion, and resonance parameters were obtained, which reproduce the initial values of the upper energy levels within a mean accuracy of 1.39 × 10-4 cm-1 for the states (110) and (011) of D2 32S, 1.61 × 10-4 cm-1 and 1.82 × 10-4 cm-1 for the states (001) and (110) of HD32S, and 2.09 × 10-4 cm-1 for the state (110) of HD34S, respectively.

Original languageEnglish
Pages (from-to)397-416
Number of pages20
JournalJournal of Molecular Spectroscopy
Volume170
Issue number2
DOIs
Publication statusPublished - Apr 1995

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Hydrogen Sulfide
hydrogen sulfide
Electron energy levels
Fourier transforms
high resolution
energy levels

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

Cite this

High Resolution Study of Deuterated Hydrogen Sulfide in the Region 2400-3000 cm-1 . / Ulenikov, O. N.; Tolchenov, R. N.; Melekhina, E. N.; Koivusaari, M.; Alanko, S.; Anttila, R.

In: Journal of Molecular Spectroscopy, Vol. 170, No. 2, 04.1995, p. 397-416.

Research output: Contribution to journalArticle

Ulenikov, ON, Tolchenov, RN, Melekhina, EN, Koivusaari, M, Alanko, S & Anttila, R 1995, 'High Resolution Study of Deuterated Hydrogen Sulfide in the Region 2400-3000 cm-1 ', Journal of Molecular Spectroscopy, vol. 170, no. 2, pp. 397-416. https://doi.org/10.1006/jmsp.1995.1080
Ulenikov, O. N. ; Tolchenov, R. N. ; Melekhina, E. N. ; Koivusaari, M. ; Alanko, S. ; Anttila, R. / High Resolution Study of Deuterated Hydrogen Sulfide in the Region 2400-3000 cm-1 In: Journal of Molecular Spectroscopy. 1995 ; Vol. 170, No. 2. pp. 397-416.
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