High resolution Fourier transform spectra of deuterated hydrogen sulfide have been recorded in the region 2400-3000 cm-1. Rotational structures of the ν1 + ν2, ν2 + ν3 bands of D2 32S, of the ν3 and ν1 + ν2 bands of HD32S, and of the ν1 + ν2 band of HD34S were analyzed. Band centers and rotational, centrifugal distortion, and resonance parameters were obtained, which reproduce the initial values of the upper energy levels within a mean accuracy of 1.39 × 10-4 cm-1 for the states (110) and (011) of D2 32S, 1.61 × 10-4 cm-1 and 1.82 × 10-4 cm-1 for the states (001) and (110) of HD32S, and 2.09 × 10-4 cm-1 for the state (110) of HD34S, respectively.
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Physical and Theoretical Chemistry