High-resolution spectroscopy of the ν2 Q branch of GeH4 with a computer-assisted, pulsed-diode laser spectrometer

Abstract

The high-resolution absorption spectrum of the Q branch of the ν₂ band of the ⁷⁴GeH₄ molecule has been recorded. The accuracy of determination the line centers was 2 × 10^-3-5 × 10^-4 cm^-1. The spectrum obtained has been interpreted. By simultaneously analyzing the states (0100, E) and (0001, F₂) spectroscopic constants have been determined for these two states, as well as resonance constants of the type of X_EF₂ ^Ω(K,Γ). The parameter values obtained reproduce the spectrum with an accuracy close to the experimental one.

Original language	English
Pages (from-to)	385-396
Number of pages	12
Journal	Journal of Molecular Spectroscopy
Volume	105
Issue number	2
DOIs	https://doi.org/10.1016/0022-2852(84)90228-5
Publication status	Published - 1984

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics

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@article{1669744f2711441dbc79c19f165a5b44,

title = "High-resolution spectroscopy of the ν2 Q branch of GeH4 with a computer-assisted, pulsed-diode laser spectrometer",

abstract = "The high-resolution absorption spectrum of the Q branch of the ν2 band of the 74GeH4 molecule has been recorded. The accuracy of determination the line centers was 2 × 10-3-5 × 10-4 cm-1. The spectrum obtained has been interpreted. By simultaneously analyzing the states (0100, E) and (0001, F2) spectroscopic constants have been determined for these two states, as well as resonance constants of the type of XEF2 Ω(K,Γ). The parameter values obtained reproduce the spectrum with an accuracy close to the experimental one.",

author = "Cheglokov, {A. E.} and Kuritsyn, {Yu A.} and Snegirev, {E. P.} and Ulenikov, {O. N.} and Vedeneeva, {G. V.}",

year = "1984",

doi = "10.1016/0022-2852(84)90228-5",

language = "English",

volume = "105",

pages = "385--396",

journal = "Journal of Molecular Spectroscopy",

issn = "0022-2852",

publisher = "Academic Press Inc.",

number = "2",

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TY - JOUR

T1 - High-resolution spectroscopy of the ν2 Q branch of GeH4 with a computer-assisted, pulsed-diode laser spectrometer

AU - Cheglokov, A. E.

AU - Kuritsyn, Yu A.

AU - Snegirev, E. P.

AU - Ulenikov, O. N.

AU - Vedeneeva, G. V.

PY - 1984

Y1 - 1984

N2 - The high-resolution absorption spectrum of the Q branch of the ν2 band of the 74GeH4 molecule has been recorded. The accuracy of determination the line centers was 2 × 10-3-5 × 10-4 cm-1. The spectrum obtained has been interpreted. By simultaneously analyzing the states (0100, E) and (0001, F2) spectroscopic constants have been determined for these two states, as well as resonance constants of the type of XEF2 Ω(K,Γ). The parameter values obtained reproduce the spectrum with an accuracy close to the experimental one.

AB - The high-resolution absorption spectrum of the Q branch of the ν2 band of the 74GeH4 molecule has been recorded. The accuracy of determination the line centers was 2 × 10-3-5 × 10-4 cm-1. The spectrum obtained has been interpreted. By simultaneously analyzing the states (0100, E) and (0001, F2) spectroscopic constants have been determined for these two states, as well as resonance constants of the type of XEF2 Ω(K,Γ). The parameter values obtained reproduce the spectrum with an accuracy close to the experimental one.

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U2 - 10.1016/0022-2852(84)90228-5

DO - 10.1016/0022-2852(84)90228-5

M3 - Article

AN - SCOPUS:23044503822

VL - 105

SP - 385

EP - 396

JO - Journal of Molecular Spectroscopy

JF - Journal of Molecular Spectroscopy

SN - 0022-2852

IS - 2

ER -

High-resolution spectroscopy of the ν₂ Q branch of GeH₄ with a computer-assisted, pulsed-diode laser spectrometer

Abstract

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