Abstract
The high-resolution spectra of AsH3 in the 8130-8340 cm-1 region, which were assigned to the (310; A1), and (310; E1), and the (310; E2) local mode combination bands, have been recorded at a resolution of 0.01 cm-1 and rotationaliy analyzed. The spectroscopic parameters were obtained by least-squares fitting. The rotational energy levels were fitted for the (310; A1) state (21 levels in all) up to J = 5, for the (310; E2) state (43 levels in all) up to J = 7, and for the (310; E1) state (43 levels in all) up to J = 5. The complication of the rotational structure indicates rotational perturbation.
| Original language | English |
|---|---|
| Pages (from-to) | 89-96 |
| Number of pages | 8 |
| Journal | Journal of Molecular Spectroscopy |
| Volume | 187 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1 Jan 1998 |
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ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Spectroscopy
- Physical and Theoretical Chemistry
Cite this
High-resolution spectroscopic study of the (310) local mode combination band system of AsH3 . / Lin, Hai; Ulenikov, Oleg N.; Yurchinko, Sergi; Wang, Xiao Gang; Zhu, Qing Shi.
In: Journal of Molecular Spectroscopy, Vol. 187, No. 1, 01.01.1998, p. 89-96.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - High-resolution spectroscopic study of the (310) local mode combination band system of AsH3
AU - Lin, Hai
AU - Ulenikov, Oleg N.
AU - Yurchinko, Sergi
AU - Wang, Xiao Gang
AU - Zhu, Qing Shi
PY - 1998/1/1
Y1 - 1998/1/1
N2 - The high-resolution spectra of AsH3 in the 8130-8340 cm-1 region, which were assigned to the (310; A1), and (310; E1), and the (310; E2) local mode combination bands, have been recorded at a resolution of 0.01 cm-1 and rotationaliy analyzed. The spectroscopic parameters were obtained by least-squares fitting. The rotational energy levels were fitted for the (310; A1) state (21 levels in all) up to J = 5, for the (310; E2) state (43 levels in all) up to J = 7, and for the (310; E1) state (43 levels in all) up to J = 5. The complication of the rotational structure indicates rotational perturbation.
AB - The high-resolution spectra of AsH3 in the 8130-8340 cm-1 region, which were assigned to the (310; A1), and (310; E1), and the (310; E2) local mode combination bands, have been recorded at a resolution of 0.01 cm-1 and rotationaliy analyzed. The spectroscopic parameters were obtained by least-squares fitting. The rotational energy levels were fitted for the (310; A1) state (21 levels in all) up to J = 5, for the (310; E2) state (43 levels in all) up to J = 7, and for the (310; E1) state (43 levels in all) up to J = 5. The complication of the rotational structure indicates rotational perturbation.
UR - http://www.scopus.com/inward/record.url?scp=0003353619&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0003353619&partnerID=8YFLogxK
U2 - 10.1006/jmsp.1997.7463
DO - 10.1006/jmsp.1997.7463
M3 - Article
VL - 187
SP - 89
EP - 96
JO - Journal of Molecular Spectroscopy
JF - Journal of Molecular Spectroscopy
SN - 0022-2852
IS - 1
ER -