Abstract
The high-resolution spectra of AsH3 in the 8130-8340 cm-1 region, which were assigned to the (310; A1), and (310; E1), and the (310; E2) local mode combination bands, have been recorded at a resolution of 0.01 cm-1 and rotationaliy analyzed. The spectroscopic parameters were obtained by least-squares fitting. The rotational energy levels were fitted for the (310; A1) state (21 levels in all) up to J = 5, for the (310; E2) state (43 levels in all) up to J = 7, and for the (310; E1) state (43 levels in all) up to J = 5. The complication of the rotational structure indicates rotational perturbation.
| Original language | English |
|---|---|
| Pages (from-to) | 89-96 |
| Number of pages | 8 |
| Journal | Journal of Molecular Spectroscopy |
| Volume | 187 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1 Jan 1998 |
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Spectroscopy
- Physical and Theoretical Chemistry
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Lin, H., Ulenikov, O. N., Yurchinko, S., Wang, X. G., & Zhu, Q. S. (1998). High-resolution spectroscopic study of the (310) local mode combination band system of AsH3 Journal of Molecular Spectroscopy, 187(1), 89-96. https://doi.org/10.1006/jmsp.1997.7463