Abstract
High resolution spectra of the coupled and degenerate (40+, 0) A1 and (40-, 0) B2 (the local mode pair) states of H2Se are reported. The vibration-rotation transitions of H2 nSe (n = 80, 78) were assigned by using the ground state combination differences and least-squares fits to yield the rotational and coupling constants for the two stretching states with degenerate band origins: v0(40+,0) = 8894·504 cm-1; v0(40-, 0) = 8894·504 cm-1. Several striking local mode limit effects and the formation of fourfold rovibrational energy clusters are observed and discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 1073-1081 |
| Number of pages | 9 |
| Journal | Molecular Physics |
| Volume | 92 |
| Issue number | 6 |
| Publication status | Published - 20 Dec 1997 |
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ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
Cite this
High resolution spectroscopic study of H2Se (40+, 0) A1 and (40-, 0) B2 stretching states : Normal mode and local mode analysis. / Zhou, Ze Yi; Wang, Xiao Gang; Zhou, Zhong Ping; Ulenikov, Oleg N.; Onopenko, Galina A.; Zhu, Qing Shi.
In: Molecular Physics, Vol. 92, No. 6, 20.12.1997, p. 1073-1081.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - High resolution spectroscopic study of H2Se (40+, 0) A1 and (40-, 0) B2 stretching states
T2 - Normal mode and local mode analysis
AU - Zhou, Ze Yi
AU - Wang, Xiao Gang
AU - Zhou, Zhong Ping
AU - Ulenikov, Oleg N.
AU - Onopenko, Galina A.
AU - Zhu, Qing Shi
PY - 1997/12/20
Y1 - 1997/12/20
N2 - High resolution spectra of the coupled and degenerate (40+, 0) A1 and (40-, 0) B2 (the local mode pair) states of H2Se are reported. The vibration-rotation transitions of H2 nSe (n = 80, 78) were assigned by using the ground state combination differences and least-squares fits to yield the rotational and coupling constants for the two stretching states with degenerate band origins: v0(40+,0) = 8894·504 cm-1; v0(40-, 0) = 8894·504 cm-1. Several striking local mode limit effects and the formation of fourfold rovibrational energy clusters are observed and discussed.
AB - High resolution spectra of the coupled and degenerate (40+, 0) A1 and (40-, 0) B2 (the local mode pair) states of H2Se are reported. The vibration-rotation transitions of H2 nSe (n = 80, 78) were assigned by using the ground state combination differences and least-squares fits to yield the rotational and coupling constants for the two stretching states with degenerate band origins: v0(40+,0) = 8894·504 cm-1; v0(40-, 0) = 8894·504 cm-1. Several striking local mode limit effects and the formation of fourfold rovibrational energy clusters are observed and discussed.
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UR - http://www.scopus.com/inward/citedby.url?scp=0011745174&partnerID=8YFLogxK
M3 - Article
VL - 92
SP - 1073
EP - 1081
JO - Molecular Physics
JF - Molecular Physics
SN - 0026-8976
IS - 6
ER -