High resolution spectroscopic study of arsine: 3v1 and 2v1 + v3 dyad: The tendency of symmetry reduction

Abstract

The high resolution spectrum of AsH₃ 3v₁ and 2v₁ + v₃ stretching overtone dyad was recorded and analyzed. The major vibration-rotation parameters of these overtones were obtained. The result indicates that these overtone vibrational states are close to the local mode limit and the rotational levels show the tendency to approach an asymmetric top.

Original language	English
Pages (from-to)	7310-7315
Number of pages	6
Journal	Journal of Chemical Physics
Volume	105
Issue number	17
Publication status	Published - 1996

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics

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title = "High resolution spectroscopic study of arsine: 3v1 and 2v1 + v3 dyad: The tendency of symmetry reduction",

abstract = "The high resolution spectrum of AsH3 3v1 and 2v1 + v3 stretching overtone dyad was recorded and analyzed. The major vibration-rotation parameters of these overtones were obtained. The result indicates that these overtone vibrational states are close to the local mode limit and the rotational levels show the tendency to approach an asymmetric top.",

author = "Ulenikov, {Oleg N.} and Sun, {Fu Ge} and Wang, {Xiao Gang} and Zhu, {Qing Shi}",

year = "1996",

language = "English",

volume = "105",

pages = "7310--7315",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics Publising LLC",

number = "17",

}

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T1 - High resolution spectroscopic study of arsine

T2 - 3v1 and 2v1 + v3 dyad: The tendency of symmetry reduction

AU - Ulenikov, Oleg N.

AU - Sun, Fu Ge

AU - Wang, Xiao Gang

AU - Zhu, Qing Shi

PY - 1996

Y1 - 1996

N2 - The high resolution spectrum of AsH3 3v1 and 2v1 + v3 stretching overtone dyad was recorded and analyzed. The major vibration-rotation parameters of these overtones were obtained. The result indicates that these overtone vibrational states are close to the local mode limit and the rotational levels show the tendency to approach an asymmetric top.

AB - The high resolution spectrum of AsH3 3v1 and 2v1 + v3 stretching overtone dyad was recorded and analyzed. The major vibration-rotation parameters of these overtones were obtained. The result indicates that these overtone vibrational states are close to the local mode limit and the rotational levels show the tendency to approach an asymmetric top.

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UR - http://www.scopus.com/inward/citedby.url?scp=0008262487&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0008262487

VL - 105

SP - 7310

EP - 7315

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 17

ER -

High resolution spectroscopic study of arsine: 3v₁ and 2v₁ + v₃ dyad: The tendency of symmetry reduction

Abstract

ASJC Scopus subject areas

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