High resolution spectroscopic study of arsine: 3v1 and 2v1 + v3 dyad: The tendency of symmetry reduction

Oleg N. Ulenikov, Fu Ge Sun, Xiao Gang Wang, Qing Shi Zhu

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43 Citations (Scopus)

Abstract

The high resolution spectrum of AsH3 3v1 and 2v1 + v3 stretching overtone dyad was recorded and analyzed. The major vibration-rotation parameters of these overtones were obtained. The result indicates that these overtone vibrational states are close to the local mode limit and the rotational levels show the tendency to approach an asymmetric top.

Original languageEnglish
Pages (from-to)7310-7315
Number of pages6
JournalJournal of Chemical Physics
Volume105
Issue number17
Publication statusPublished - 1996

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

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