High-resolution spectroscopic study of 2ν1, 2ν3 and ν1 + ν3 stretching states: The local-mode effects of H2Se

Oleg N. Ulenikov, Assia B. Malikova, Hua Feng Li, Hai Bo Qian, Qing Shi Zhu, B. A. Thrush

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Abstract

High-resolution spectra of the coupled 2ν1, 2ν3 and ν1 + ν3 states of H2Se have been studied. The vibration-rotation transitions of H2 nSe (n = 82, 80, 78, 77 and 76) were assigned by using the ground-state combination differences and least-squares fitted to yield the vibration-rotation parameters. Several striking local-mode effects are observed and discussed.

Original languageEnglish
Pages (from-to)13-16
Number of pages4
JournalJournal of the Chemical Society, Faraday Transactions
Volume91
Issue number1
DOIs
Publication statusPublished - 1 Dec 1995

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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