High-resolution rotational analysis of the lowest D-O overtone bands of deuterated hypochlorous acid

2v1 and 3v1

Yun Ding, O. N. Ulenikov, E. S. Bekhtereva, Jing Jing Zheng, Sheng Gui He, Xiang Huai Wang, Shui Ming Hu, Qing Shi Zhu

Research output: Contribution to journalArticle

Abstract

The high-resolution Fourier transform spectrum of the DO35Cl molecule was recorded and analyzed in the region of the two lowest D-O overtone bands, 2v1 and 3v1. Because of the presence of strong resonance interactions, the influence of the (130) state on the (200) state, and also that of the (221), (230) states on the (300) sate, was taken into account. Transitions belonging to the 2v1 and 3v1 bands were assigned up to Jmax = 35 in both cases. The sets of spectroscopic parameters and resonance coefficients obtained from the fit reproduce the "experimental" rovibrational energies of the (200) and (300) vibrational states with accuracies close to experimental uncertainties.

Original languageEnglish
Article number98422
Pages (from-to)233-241
Number of pages9
JournalJournal of Molecular Spectroscopy
Volume209
Issue number2
DOIs
Publication statusPublished - 1 Jan 2001

Fingerprint

Hypochlorous Acid
harmonics
acids
high resolution
vibrational states
Fourier transforms
Molecules
coefficients
molecules
interactions
energy
Uncertainty

Keywords

  • DOCl molecule
  • Rotation-vibration spectra
  • Spectroscopic parameters

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

Cite this

High-resolution rotational analysis of the lowest D-O overtone bands of deuterated hypochlorous acid : 2v1 and 3v1. / Ding, Yun; Ulenikov, O. N.; Bekhtereva, E. S.; Zheng, Jing Jing; He, Sheng Gui; Wang, Xiang Huai; Hu, Shui Ming; Zhu, Qing Shi.

In: Journal of Molecular Spectroscopy, Vol. 209, No. 2, 98422, 01.01.2001, p. 233-241.

Research output: Contribution to journalArticle

Ding, Yun ; Ulenikov, O. N. ; Bekhtereva, E. S. ; Zheng, Jing Jing ; He, Sheng Gui ; Wang, Xiang Huai ; Hu, Shui Ming ; Zhu, Qing Shi. / High-resolution rotational analysis of the lowest D-O overtone bands of deuterated hypochlorous acid : 2v1 and 3v1. In: Journal of Molecular Spectroscopy. 2001 ; Vol. 209, No. 2. pp. 233-241.
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AU - Zheng, Jing Jing

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