Abstract
The high-resolution Fourier transform spectrum of the DO35Cl molecule was recorded and analyzed in the region of the two lowest D-O overtone bands, 2v1 and 3v1. Because of the presence of strong resonance interactions, the influence of the (130) state on the (200) state, and also that of the (221), (230) states on the (300) sate, was taken into account. Transitions belonging to the 2v1 and 3v1 bands were assigned up to Jmax = 35 in both cases. The sets of spectroscopic parameters and resonance coefficients obtained from the fit reproduce the "experimental" rovibrational energies of the (200) and (300) vibrational states with accuracies close to experimental uncertainties.
| Original language | English |
|---|---|
| Article number | 98422 |
| Pages (from-to) | 233-241 |
| Number of pages | 9 |
| Journal | Journal of Molecular Spectroscopy |
| Volume | 209 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 1 Jan 2001 |
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Keywords
- DOCl molecule
- Rotation-vibration spectra
- Spectroscopic parameters
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Spectroscopy
- Physical and Theoretical Chemistry
Cite this
High-resolution rotational analysis of the lowest D-O overtone bands of deuterated hypochlorous acid : 2v1 and 3v1. / Ding, Yun; Ulenikov, O. N.; Bekhtereva, E. S.; Zheng, Jing Jing; He, Sheng Gui; Wang, Xiang Huai; Hu, Shui Ming; Zhu, Qing Shi.
In: Journal of Molecular Spectroscopy, Vol. 209, No. 2, 98422, 01.01.2001, p. 233-241.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - High-resolution rotational analysis of the lowest D-O overtone bands of deuterated hypochlorous acid
T2 - 2v1 and 3v1
AU - Ding, Yun
AU - Ulenikov, O. N.
AU - Bekhtereva, E. S.
AU - Zheng, Jing Jing
AU - He, Sheng Gui
AU - Wang, Xiang Huai
AU - Hu, Shui Ming
AU - Zhu, Qing Shi
PY - 2001/1/1
Y1 - 2001/1/1
N2 - The high-resolution Fourier transform spectrum of the DO35Cl molecule was recorded and analyzed in the region of the two lowest D-O overtone bands, 2v1 and 3v1. Because of the presence of strong resonance interactions, the influence of the (130) state on the (200) state, and also that of the (221), (230) states on the (300) sate, was taken into account. Transitions belonging to the 2v1 and 3v1 bands were assigned up to Jmax = 35 in both cases. The sets of spectroscopic parameters and resonance coefficients obtained from the fit reproduce the "experimental" rovibrational energies of the (200) and (300) vibrational states with accuracies close to experimental uncertainties.
AB - The high-resolution Fourier transform spectrum of the DO35Cl molecule was recorded and analyzed in the region of the two lowest D-O overtone bands, 2v1 and 3v1. Because of the presence of strong resonance interactions, the influence of the (130) state on the (200) state, and also that of the (221), (230) states on the (300) sate, was taken into account. Transitions belonging to the 2v1 and 3v1 bands were assigned up to Jmax = 35 in both cases. The sets of spectroscopic parameters and resonance coefficients obtained from the fit reproduce the "experimental" rovibrational energies of the (200) and (300) vibrational states with accuracies close to experimental uncertainties.
KW - DOCl molecule
KW - Rotation-vibration spectra
KW - Spectroscopic parameters
UR - http://www.scopus.com/inward/record.url?scp=0035742222&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0035742222&partnerID=8YFLogxK
U2 - 10.1006/jmsp.2001.8422
DO - 10.1006/jmsp.2001.8422
M3 - Article
VL - 209
SP - 233
EP - 241
JO - Journal of Molecular Spectroscopy
JF - Journal of Molecular Spectroscopy
SN - 0022-2852
IS - 2
M1 - 98422
ER -