High-Resolution Infrared Study of PHD2: The P–H Stretching Bands ν1 and 2ν1

Abstract

For the first time the infrared spectrum of PHD₂ was recorded in the region of the PH stretching fundamental ν₁ at 2324.005 cm^-1 and the overtone 2ν₁ at 4563.634 cm^-1 with a resolution of 4.2 × 10^-3 cm^-1 and 8.8 × 10^-3 cm^-1, respectively. In the analyses about 1340 and 1020 transitions were assigned to the corresponding ν₁ and 2ν₁ bands, which provided 316 and 248 upper energies, respectively. Since both the bands are sufficiently isolated, a standard Watson-type Hamiltonian (A-reduction, I^r-representation) was employed. The obtained sets of spectroscopic parameters correlate very well both with each other, and with the corresponding parameters of the ground vibrational state.

Original language	English
Pages (from-to)	85-92
Number of pages	8
Journal	Journal of Molecular Spectroscopy
Volume	215
Issue number	1
DOIs	https://doi.org/10.1006/jmsp.2002.8603
Publication status	Published - 1 Jan 2002

Keywords

PHD molecule
Spectroscopic parameters
Vibration-rotation spectra

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry

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10.1006/jmsp.2002.8603

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@article{dc6a826f018f4790afd9bafc059144e0,

title = "High-Resolution Infrared Study of PHD2: The P–H Stretching Bands ν1 and 2ν1",

abstract = "For the first time the infrared spectrum of PHD2 was recorded in the region of the PH stretching fundamental ν1 at 2324.005 cm-1 and the overtone 2ν1 at 4563.634 cm-1 with a resolution of 4.2 × 10-3 cm-1 and 8.8 × 10-3 cm-1, respectively. In the analyses about 1340 and 1020 transitions were assigned to the corresponding ν1 and 2ν1 bands, which provided 316 and 248 upper energies, respectively. Since both the bands are sufficiently isolated, a standard Watson-type Hamiltonian (A-reduction, Ir-representation) was employed. The obtained sets of spectroscopic parameters correlate very well both with each other, and with the corresponding parameters of the ground vibrational state.",

keywords = "PHD molecule, Spectroscopic parameters, Vibration-rotation spectra",

author = "Ulenikov, {O. N.} and Petrunina, {O. L.} and Bekhtereva, {E. S.} and Sinitsyn, {Evguenii Alexandrovich} and H. B{\"u}rger and W. Jerzembeck",

year = "2002",

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doi = "10.1006/jmsp.2002.8603",

language = "English",

volume = "215",

pages = "85--92",

journal = "Journal of Molecular Spectroscopy",

issn = "0022-2852",

publisher = "Academic Press Inc.",

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TY - JOUR

T1 - High-Resolution Infrared Study of PHD2

T2 - The P–H Stretching Bands ν1 and 2ν1

AU - Ulenikov, O. N.

AU - Petrunina, O. L.

AU - Bekhtereva, E. S.

AU - Sinitsyn, Evguenii Alexandrovich

AU - Bürger, H.

AU - Jerzembeck, W.

PY - 2002/1/1

Y1 - 2002/1/1

N2 - For the first time the infrared spectrum of PHD2 was recorded in the region of the PH stretching fundamental ν1 at 2324.005 cm-1 and the overtone 2ν1 at 4563.634 cm-1 with a resolution of 4.2 × 10-3 cm-1 and 8.8 × 10-3 cm-1, respectively. In the analyses about 1340 and 1020 transitions were assigned to the corresponding ν1 and 2ν1 bands, which provided 316 and 248 upper energies, respectively. Since both the bands are sufficiently isolated, a standard Watson-type Hamiltonian (A-reduction, Ir-representation) was employed. The obtained sets of spectroscopic parameters correlate very well both with each other, and with the corresponding parameters of the ground vibrational state.

AB - For the first time the infrared spectrum of PHD2 was recorded in the region of the PH stretching fundamental ν1 at 2324.005 cm-1 and the overtone 2ν1 at 4563.634 cm-1 with a resolution of 4.2 × 10-3 cm-1 and 8.8 × 10-3 cm-1, respectively. In the analyses about 1340 and 1020 transitions were assigned to the corresponding ν1 and 2ν1 bands, which provided 316 and 248 upper energies, respectively. Since both the bands are sufficiently isolated, a standard Watson-type Hamiltonian (A-reduction, Ir-representation) was employed. The obtained sets of spectroscopic parameters correlate very well both with each other, and with the corresponding parameters of the ground vibrational state.

KW - PHD molecule

KW - Spectroscopic parameters

KW - Vibration-rotation spectra

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High-Resolution Infrared Study of PHD₂: The P–H Stretching Bands ν₁ and 2ν₁

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Fingerprint Dive into the research topics of 'High-Resolution Infrared Study of PHD<sub>2</sub>: The P–H Stretching Bands ν<sub>1</sub> and 2ν<sub>1</sub>'. Together they form a unique fingerprint.

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