Abstract
A high resolution spectrum of the formaldehyde D2 12CO molecule in the range from 1780 to 2400 cm-1 has been recorded by a Fourier transform infrared spectrometer. The measured region covers the stretching fundamental bands ν1 and ν5 and the first overtone and combination bands 2ν4, ν4+ν 6, 2ν6, ν3+ν4, ν3+ν6, and 2ν3 which correspond to double excitations of deformational quanta. About 9600 transitions were assigned to the eight mentioned vibrational bands. Preliminary analysis with J′<10 of the obtained assignments was made, and the values of the band centers and the main rotational, centrifugal distortion, and resonance interaction parameters were estimated.
Original language | English |
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Pages (from-to) | 182-205 |
Number of pages | 24 |
Journal | Journal of Molecular Structure |
Volume | 780-781 |
Issue number | SPEC. ISS. |
DOIs | |
Publication status | Published - 3 Jan 2006 |
Keywords
- D CO
- Formaldehyde
ASJC Scopus subject areas
- Structural Biology
- Organic Chemistry
- Physical and Theoretical Chemistry
- Spectroscopy
- Atomic and Molecular Physics, and Optics
- Materials Science (miscellaneous)