High Resolution Infrared Spectrum of the ν78 Band of the Trans-C2H2D2 Molecule

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6 Citations (Scopus)

Abstract

High resolution spectrum of the trans-C2H2D2 molecule is analyzed on the basis of the Ground State Combination Difference method in the region 1450–1650 cm–1, in which the hybrid ν7 + ν8 band is located. The analysis is performed in the framework of the model which takes into account the Coriolis interaction with the ν8 + ν10 band. The b-type transitions that in their turn, allow more experimental data on the ν7 + ν8 band to be obtained, are determined for this band for the first time.

Original languageEnglish
Pages (from-to)1-6
Number of pages6
JournalRussian Physics Journal
DOIs
Publication statusAccepted/In press - 11 Feb 2017

Fingerprint

infrared spectra
high resolution
molecules
ground state
interactions

Keywords

  • ethylene isotopologue
  • matrix of interacting states
  • vibrational-rotational spectrum

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

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title = "High Resolution Infrared Spectrum of the ν7+ν8 Band of the Trans-C2H2D2 Molecule",
abstract = "High resolution spectrum of the trans-C2H2D2 molecule is analyzed on the basis of the Ground State Combination Difference method in the region 1450–1650 cm–1, in which the hybrid ν7 + ν8 band is located. The analysis is performed in the framework of the model which takes into account the Coriolis interaction with the ν8 + ν10 band. The b-type transitions that in their turn, allow more experimental data on the ν7 + ν8 band to be obtained, are determined for this band for the first time.",
keywords = "ethylene isotopologue, matrix of interacting states, vibrational-rotational spectrum",
author = "Ziatkova, {A. G.} and Aslapovskaya, {Y. S.} and Gromova, {O. V.} and Bekhtereva, {E. S.} and Fomchenko, {A. L.}",
year = "2017",
month = "2",
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doi = "10.1007/s11182-017-0951-8",
language = "English",
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T1 - High Resolution Infrared Spectrum of the ν7+ν8 Band of the Trans-C2H2D2 Molecule

AU - Ziatkova, A. G.

AU - Aslapovskaya, Y. S.

AU - Gromova, O. V.

AU - Bekhtereva, E. S.

AU - Fomchenko, A. L.

PY - 2017/2/11

Y1 - 2017/2/11

N2 - High resolution spectrum of the trans-C2H2D2 molecule is analyzed on the basis of the Ground State Combination Difference method in the region 1450–1650 cm–1, in which the hybrid ν7 + ν8 band is located. The analysis is performed in the framework of the model which takes into account the Coriolis interaction with the ν8 + ν10 band. The b-type transitions that in their turn, allow more experimental data on the ν7 + ν8 band to be obtained, are determined for this band for the first time.

AB - High resolution spectrum of the trans-C2H2D2 molecule is analyzed on the basis of the Ground State Combination Difference method in the region 1450–1650 cm–1, in which the hybrid ν7 + ν8 band is located. The analysis is performed in the framework of the model which takes into account the Coriolis interaction with the ν8 + ν10 band. The b-type transitions that in their turn, allow more experimental data on the ν7 + ν8 band to be obtained, are determined for this band for the first time.

KW - ethylene isotopologue

KW - matrix of interacting states

KW - vibrational-rotational spectrum

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