Abstract
The high resolution infrared spectra of the 32S16O18O molecule were recorded for the first time with a Bruker IFS 120 HR Fourier transform interferometer and analysed in the region of 1550-1950cm-1 where the bands ν1+ν2 and ν2+ν3 are located. About 1050 and 1570 transitions were assigned in the experimental spectra with the maximum values of quantum numbers Jmax./Kamax. equal to 64/16 and 58/19 to the bands ν1+ν2 and ν2+ν3, respectively. The subsequent weighted fit of experimentally assigned transitions was made with the Hamiltonian model which takes into account the resonance interactions between the studied vibrational states. As the result, a set of 16 fitted parameters was obtained which reproduces the initial 1442 ro-vibrational energy values obtained from the assigned transitions with the drms=3.7×10-4cm-1. An analysis of more than 4050 experimental ro-vibrational line intensities of the ν1+ν2 and ν2+ν3 bands of 32S16O2 was made, and a set of 7 effective dipole moment parameters was obtained which reproduce the initial experimental line intensities with the drms=6.9%. Values of these parameters, being re-calculated to the values of corresponding parameters of the 34S16O2, 32S18O2 and 32S16O18O species were used for calculation of line intensities in the ν1+ν2 and ν2+ν3 bands of these three isotopologues. A list of transitions with their line intensities in the region of 1550-1950cm-1 for the four mentioned species is generated.
| Original language | English |
|---|---|
| Journal | Journal of Quantitative Spectroscopy and Radiative Transfer |
| DOIs | |
| Publication status | Accepted/In press - 12 Jan 2017 |
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Keywords
- High resolution spectrum of sulfur dioxide species
- Intensities
- Line positions
- The ν1+ν2/ν2+ν3 interacting states of sulfur dioxide
ASJC Scopus subject areas
- Radiation
- Atomic and Molecular Physics, and Optics
- Spectroscopy
Cite this
High resolution FTIR spectroscopy of sulfur dioxide in the 1550-1950cm-1 region : First analysis of the ν1+ν2/ν2+ν3 bands of 32S16O18O and experimental line intensities of ro-vibrational transitions in the ν1+thomampe. / Ulenikov, O. N.; Bekhtereva, E. S.; Gromova, O. V.; Horneman, V. M.; Sydow, C.; Bauerecker, S.
In: Journal of Quantitative Spectroscopy and Radiative Transfer, 12.01.2017.Research output: Contribution to journal › Article
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TY - JOUR
T1 - High resolution FTIR spectroscopy of sulfur dioxide in the 1550-1950cm-1 region
T2 - First analysis of the ν1+ν2/ν2+ν3 bands of 32S16O18O and experimental line intensities of ro-vibrational transitions in the ν1+thomampe
AU - Ulenikov, O. N.
AU - Bekhtereva, E. S.
AU - Gromova, O. V.
AU - Horneman, V. M.
AU - Sydow, C.
AU - Bauerecker, S.
PY - 2017/1/12
Y1 - 2017/1/12
N2 - The high resolution infrared spectra of the 32S16O18O molecule were recorded for the first time with a Bruker IFS 120 HR Fourier transform interferometer and analysed in the region of 1550-1950cm-1 where the bands ν1+ν2 and ν2+ν3 are located. About 1050 and 1570 transitions were assigned in the experimental spectra with the maximum values of quantum numbers Jmax./Kamax. equal to 64/16 and 58/19 to the bands ν1+ν2 and ν2+ν3, respectively. The subsequent weighted fit of experimentally assigned transitions was made with the Hamiltonian model which takes into account the resonance interactions between the studied vibrational states. As the result, a set of 16 fitted parameters was obtained which reproduces the initial 1442 ro-vibrational energy values obtained from the assigned transitions with the drms=3.7×10-4cm-1. An analysis of more than 4050 experimental ro-vibrational line intensities of the ν1+ν2 and ν2+ν3 bands of 32S16O2 was made, and a set of 7 effective dipole moment parameters was obtained which reproduce the initial experimental line intensities with the drms=6.9%. Values of these parameters, being re-calculated to the values of corresponding parameters of the 34S16O2, 32S18O2 and 32S16O18O species were used for calculation of line intensities in the ν1+ν2 and ν2+ν3 bands of these three isotopologues. A list of transitions with their line intensities in the region of 1550-1950cm-1 for the four mentioned species is generated.
AB - The high resolution infrared spectra of the 32S16O18O molecule were recorded for the first time with a Bruker IFS 120 HR Fourier transform interferometer and analysed in the region of 1550-1950cm-1 where the bands ν1+ν2 and ν2+ν3 are located. About 1050 and 1570 transitions were assigned in the experimental spectra with the maximum values of quantum numbers Jmax./Kamax. equal to 64/16 and 58/19 to the bands ν1+ν2 and ν2+ν3, respectively. The subsequent weighted fit of experimentally assigned transitions was made with the Hamiltonian model which takes into account the resonance interactions between the studied vibrational states. As the result, a set of 16 fitted parameters was obtained which reproduces the initial 1442 ro-vibrational energy values obtained from the assigned transitions with the drms=3.7×10-4cm-1. An analysis of more than 4050 experimental ro-vibrational line intensities of the ν1+ν2 and ν2+ν3 bands of 32S16O2 was made, and a set of 7 effective dipole moment parameters was obtained which reproduce the initial experimental line intensities with the drms=6.9%. Values of these parameters, being re-calculated to the values of corresponding parameters of the 34S16O2, 32S18O2 and 32S16O18O species were used for calculation of line intensities in the ν1+ν2 and ν2+ν3 bands of these three isotopologues. A list of transitions with their line intensities in the region of 1550-1950cm-1 for the four mentioned species is generated.
KW - High resolution spectrum of sulfur dioxide species
KW - Intensities
KW - Line positions
KW - The ν1+ν2/ν2+ν3 interacting states of sulfur dioxide
UR - http://www.scopus.com/inward/record.url?scp=85014774000&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85014774000&partnerID=8YFLogxK
U2 - 10.1016/j.jqsrt.2017.02.005
DO - 10.1016/j.jqsrt.2017.02.005
M3 - Article
AN - SCOPUS:85014774000
JO - Journal of Quantitative Spectroscopy and Radiative Transfer
JF - Journal of Quantitative Spectroscopy and Radiative Transfer
SN - 0022-4073
ER -