Abstract
The high-resolution Fourier transform spectra of the CHD3 molecule have been recorded and assigned between 1850 and 2450 cm-1. To verify the assignments and to span a more complete energy manifold in the excited vibrational states, the hot bands 2v3 - v3, v3 + v6 - v3, v3 + v6 - v6, and 2v6 - v6 near 1000 cm-1 were used. The assignment presented in this study is based on the recent ground state rotational energies determined by Ulenikov et al. (J. Mol. Spectrosc. 186 (1997) 230). As a result the vibrational-rotational energies in the (v3 = 2,A1), (v3 = v6 = 1,E), (v6 = 2,A1), (v6 = 2,E), (v4 = 1,E), (v2 = 1,A1), and (v3 = v5 = 1,E) states have been refined and extended. (C) 2000 Elsevier Science B.V.
| Original language | English |
|---|---|
| Pages (from-to) | 25-40 |
| Number of pages | 16 |
| Journal | Journal of Molecular Structure |
| Volume | 517-518 |
| DOIs | |
| Publication status | Published - 16 Feb 2000 |
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Keywords
- CHCD molecule
- High-resolution Fourier transform IR spectrum
ASJC Scopus subject areas
- Structural Biology
- Organic Chemistry
- Physical and Theoretical Chemistry
- Spectroscopy
- Atomic and Molecular Physics, and Optics
Cite this
High-resolution Fourier transform spectrum of the CHD3 molecule in the region of 1850-2450 cm-1 : Assignment and preliminary analysis. / Ulenikov, O. N.; Onopenko, G. A.; Tyabaeva, N. E.; Schroderus, J.; Alanko, S.; Koivusaari, M.
In: Journal of Molecular Structure, Vol. 517-518, 16.02.2000, p. 25-40.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - High-resolution Fourier transform spectrum of the CHD3 molecule in the region of 1850-2450 cm-1
T2 - Assignment and preliminary analysis
AU - Ulenikov, O. N.
AU - Onopenko, G. A.
AU - Tyabaeva, N. E.
AU - Schroderus, J.
AU - Alanko, S.
AU - Koivusaari, M.
PY - 2000/2/16
Y1 - 2000/2/16
N2 - The high-resolution Fourier transform spectra of the CHD3 molecule have been recorded and assigned between 1850 and 2450 cm-1. To verify the assignments and to span a more complete energy manifold in the excited vibrational states, the hot bands 2v3 - v3, v3 + v6 - v3, v3 + v6 - v6, and 2v6 - v6 near 1000 cm-1 were used. The assignment presented in this study is based on the recent ground state rotational energies determined by Ulenikov et al. (J. Mol. Spectrosc. 186 (1997) 230). As a result the vibrational-rotational energies in the (v3 = 2,A1), (v3 = v6 = 1,E), (v6 = 2,A1), (v6 = 2,E), (v4 = 1,E), (v2 = 1,A1), and (v3 = v5 = 1,E) states have been refined and extended. (C) 2000 Elsevier Science B.V.
AB - The high-resolution Fourier transform spectra of the CHD3 molecule have been recorded and assigned between 1850 and 2450 cm-1. To verify the assignments and to span a more complete energy manifold in the excited vibrational states, the hot bands 2v3 - v3, v3 + v6 - v3, v3 + v6 - v6, and 2v6 - v6 near 1000 cm-1 were used. The assignment presented in this study is based on the recent ground state rotational energies determined by Ulenikov et al. (J. Mol. Spectrosc. 186 (1997) 230). As a result the vibrational-rotational energies in the (v3 = 2,A1), (v3 = v6 = 1,E), (v6 = 2,A1), (v6 = 2,E), (v4 = 1,E), (v2 = 1,A1), and (v3 = v5 = 1,E) states have been refined and extended. (C) 2000 Elsevier Science B.V.
KW - CHCD molecule
KW - High-resolution Fourier transform IR spectrum
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U2 - 10.1016/S0022-2860(99)00236-7
DO - 10.1016/S0022-2860(99)00236-7
M3 - Article
VL - 517-518
SP - 25
EP - 40
JO - Journal of Molecular Structure
JF - Journal of Molecular Structure
SN - 0022-2860
ER -