High-resolution fourier transform spectra of CH2D2: pentade of the lowest interacting vibrational bands ν4(A1), ν7(B1), ν9(B2), ν5(A2), and ν3(A1)

Abstract

The spectrum of CH₂D₂ has been recorded with a Fourier transform Bruker IFS HR spectrometer with a resolution of 0.003 cm^-1. From 4200 lines recorded in the 900-1550 cm^-1 region, 861 have been assigned to ν₄(A₁), 954 to ν₇(B₁), 859 to ν₉(B₂), and 763 to ν₃(A₁) absorption bands, respectively. Simultaneous fitting of all experimental data has been made. Rotational, centrifugal, and resonance parameters obtained reproduce the initial experimental data within an average accuracy of 15 × 10^-5 cm^-1.

Original language	English
Pages (from-to)	109-130
Number of pages	22
Journal	Journal of Molecular Spectroscopy
Volume	167
Issue number	1
DOIs	https://doi.org/10.1006/jmsp.1994.1221
Publication status	Published - Sep 1994

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics

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10.1006/jmsp.1994.1221

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High-resolution fourier transform spectra of CH₂D₂ : pentade of the lowest interacting vibrational bands ν₄(A₁), ν₇(B₁), ν₉(B₂), ν₅(A₂), and ν₃(A₁). / Ulenikov, O. N.; Tolchenov, R. N.; Koivusaari, M.; Alanko, S.; Anttila, R.

In: Journal of Molecular Spectroscopy, Vol. 167, No. 1, 09.1994, p. 109-130.

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abstract = "The spectrum of CH2D2 has been recorded with a Fourier transform Bruker IFS HR spectrometer with a resolution of 0.003 cm-1. From 4200 lines recorded in the 900-1550 cm-1 region, 861 have been assigned to ν4(A1), 954 to ν7(B1), 859 to ν9(B2), and 763 to ν3(A1) absorption bands, respectively. Simultaneous fitting of all experimental data has been made. Rotational, centrifugal, and resonance parameters obtained reproduce the initial experimental data within an average accuracy of 15 × 10-5 cm-1.",

author = "Ulenikov, {O. N.} and Tolchenov, {R. N.} and M. Koivusaari and S. Alanko and R. Anttila",

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T2 - pentade of the lowest interacting vibrational bands ν4(A1), ν7(B1), ν9(B2), ν5(A2), and ν3(A1)

AU - Ulenikov, O. N.

AU - Tolchenov, R. N.

AU - Koivusaari, M.

AU - Alanko, S.

AU - Anttila, R.

PY - 1994/9

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N2 - The spectrum of CH2D2 has been recorded with a Fourier transform Bruker IFS HR spectrometer with a resolution of 0.003 cm-1. From 4200 lines recorded in the 900-1550 cm-1 region, 861 have been assigned to ν4(A1), 954 to ν7(B1), 859 to ν9(B2), and 763 to ν3(A1) absorption bands, respectively. Simultaneous fitting of all experimental data has been made. Rotational, centrifugal, and resonance parameters obtained reproduce the initial experimental data within an average accuracy of 15 × 10-5 cm-1.

AB - The spectrum of CH2D2 has been recorded with a Fourier transform Bruker IFS HR spectrometer with a resolution of 0.003 cm-1. From 4200 lines recorded in the 900-1550 cm-1 region, 861 have been assigned to ν4(A1), 954 to ν7(B1), 859 to ν9(B2), and 763 to ν3(A1) absorption bands, respectively. Simultaneous fitting of all experimental data has been made. Rotational, centrifugal, and resonance parameters obtained reproduce the initial experimental data within an average accuracy of 15 × 10-5 cm-1.

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