High-resolution fourier transform spectra of CH2D2: pentade of the lowest interacting vibrational bands ν4(A1), ν7(B1), ν9(B2), ν5(A2), and ν3(A1)

O. N. Ulenikov, R. N. Tolchenov, M. Koivusaari, S. Alanko, R. Anttila

Research output: Contribution to journalArticle

43 Citations (Scopus)

Abstract

The spectrum of CH2D2 has been recorded with a Fourier transform Bruker IFS HR spectrometer with a resolution of 0.003 cm-1. From 4200 lines recorded in the 900-1550 cm-1 region, 861 have been assigned to ν4(A1), 954 to ν7(B1), 859 to ν9(B2), and 763 to ν3(A1) absorption bands, respectively. Simultaneous fitting of all experimental data has been made. Rotational, centrifugal, and resonance parameters obtained reproduce the initial experimental data within an average accuracy of 15 × 10-5 cm-1.

Original languageEnglish
Pages (from-to)109-130
Number of pages22
JournalJournal of Molecular Spectroscopy
Volume167
Issue number1
DOIs
Publication statusPublished - Sep 1994

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

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