High-Resolution Fourier Transform Spectra of AsH3

Transitions to the Interacting Sublevels of the v4 = 2 State

O. N. Ulenikov, A. B. Malikova, B. P. Winnewisser, M. Winnewisser

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The high-resolution Fourier transform spectrum of the 2ν4 absorption band of the AsH3 molecule is analyzed. About 900 transitions (about 55% of them "forbidden") are assigned to the two components of the 2ν4 band. A set of parameters, including rotational and centrifugal distortion constants and splitting and resonance parameters, is obtained which reproduces the initial experimental data within an rms deviation of 0.006 cm-1.

Original languageEnglish
Pages (from-to)330-343
Number of pages14
JournalJournal of Molecular Spectroscopy
Volume172
Issue number2
DOIs
Publication statusPublished - Aug 1995

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Absorption spectra
Fourier transforms
Molecules
high resolution
absorption spectra
deviation
molecules
arsine

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

Cite this

High-Resolution Fourier Transform Spectra of AsH3 : Transitions to the Interacting Sublevels of the v4 = 2 State. / Ulenikov, O. N.; Malikova, A. B.; Winnewisser, B. P.; Winnewisser, M.

In: Journal of Molecular Spectroscopy, Vol. 172, No. 2, 08.1995, p. 330-343.

Research output: Contribution to journalArticle

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