High-resolution Fourier-transform intracavity laser absorption spectroscopy of D2O in the region of the 4v1 + v3 band

Shui Ming Hu, O. N. Ulenikov, E. S. Bekhtereva, G. A. Onopenko, Sheng Gui He, Hai Lin, Ji Xin Cheng, Qing Shi Zhu

Research output: Contribution to journalArticle

42 Citations (Scopus)

Abstract

The high-resolution absorption spectrum of the D2O molecule was recorded with the Fourier-transform intracavity laser absorption spectrometer in the region 12570-12820 cm-1 where the band 4ν1 + ν3 is located. Transitions belonging to the 4ν1 + ν3 band, and the bands 3ν1 + 2ν3 and 3ν1 + 2ν2 + ν3, of which the up states are strongly interacted with that of the 4ν1 + ν3, were assigned in the recorded spectrum. Up state energy levels were fitted to derive effective spectroscopic parameters, which reproduce majority of the assigned transitions within the experimental accuracy.

Original languageEnglish
Article number98526
Pages (from-to)89-95
Number of pages7
JournalJournal of Molecular Spectroscopy
Volume212
Issue number1
DOIs
Publication statusPublished - 1 Jan 2002

Keywords

  • DO molecule
  • Intracavity laser absorption spectroscopy
  • Spectroscopic parameters
  • Vibration-rotation spectra

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

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