Heulandite/polyaniline hybrid composite for efficient removal of acidic dye from water; kinetic, equilibrium studies and statistical optimization

Mostafa R. Abukhadra, Mohamed Rabia, Mohamed Shaban, Francis Verpoort

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

Heulandite/polyaniline (HU/PANI) composite was prepared by mechanical mixing from natural heulandite and synthesized polyaniline. HU/PANI was characterized by XRD, SEM, TEM, FT-IR, and UV–Vis spectroscopy. The product is of polycrystalline nature with an average crystallite size of 25.7 nm and optical band gap of 1.69 eV. HU/PANI shows higher efficiency in the removal of light green SF dye than natural HU or PANI in the dark and under artificial illumination. The equilibrium time was attained after 360 and 480 min in the dark and under illumination, respectively. The results fitted well with pseudo second order and Elovich kinetic models. The adsorption isotherm in the dark fitted well with Langmuir isotherm model and the calculated qmax was 44.6 mg/g. Using illumination, the data fitted better with the Freundlich and Temkin model than with the Langmuir model. Based on response surface analysis, the predicted conditions for maximum removal of light green SF dye in the dark (70.9%) were 5.5 mg/L, 24 mg, 3, and 430 min for dye concentration, HU/PANI dose, pH, and contact time, respectively. Whereas, under light illumination (97%) at operating conditions of 15 mg/L, 15 mg, 3, and 589 min, respectively. The composite also shows high efficiencies in the removal of other types of acidic and basic dyes.

Original languageEnglish
Pages (from-to)2501-2511
Number of pages11
JournalAdvanced Powder Technology
Volume29
Issue number10
DOIs
Publication statusPublished - 1 Oct 2018

Keywords

  • Characterization
  • Isotherm modeling
  • Kinetic studies
  • Polyaniline/heulandite composite
  • Response surface

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Mechanics of Materials

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