TY - JOUR
T1 - Helium broadening parameters of water vapor in the 10,200–11,200 cm−1 spectral region
AU - Petrova, T. M.
AU - Solodov, A. M.
AU - Solodov, A. A.
AU - Deichuli, V. M.
AU - Starikov, V. I.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - The He-broadening (γ) and shift (δ) coefficients of 76 rovibrational transitions belonging to the 3ν1, 3ν3, ν1 + 2ν2 + ν3, and 2ν1 + ν3 vibrational bands of H2O molecule were measured in the spectral range between 10,200 and 11,200 cm−1 with the spectral resolution of 0.01 cm−1 using a Bruker IFS 125HR FTIR spectrometer. The calculations of γ and δ were performed in the framework of the semi-classical method. It was shown that the vibrational dependence of the long-range as well as the short-range parts of an isotropic H2O-He interaction potential influence substantially the calculated broadening coefficients γ. The vibrationally and rotationally dependent analytical model for the broadening coefficients calculation is presented and discussed.
AB - The He-broadening (γ) and shift (δ) coefficients of 76 rovibrational transitions belonging to the 3ν1, 3ν3, ν1 + 2ν2 + ν3, and 2ν1 + ν3 vibrational bands of H2O molecule were measured in the spectral range between 10,200 and 11,200 cm−1 with the spectral resolution of 0.01 cm−1 using a Bruker IFS 125HR FTIR spectrometer. The calculations of γ and δ were performed in the framework of the semi-classical method. It was shown that the vibrational dependence of the long-range as well as the short-range parts of an isotropic H2O-He interaction potential influence substantially the calculated broadening coefficients γ. The vibrationally and rotationally dependent analytical model for the broadening coefficients calculation is presented and discussed.
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U2 - 10.1016/j.jms.2016.11.006
DO - 10.1016/j.jms.2016.11.006
M3 - Article
AN - SCOPUS:84997170450
VL - 331
SP - 60
EP - 65
JO - Journal of Molecular Spectroscopy
JF - Journal of Molecular Spectroscopy
SN - 0022-2852
ER -