Abstract
The chromatographic properties of zirconium(IV) acetylacetonate with grafted L-arginine were studied. The thermodynamic parameters of the retention of enantiomers of trimethylsilyl derivatives of amino acids on this stationary phase were determined. It was shown that the energy difference of sorbate-sorbent complexation is high enough to separate racemic mixtures.
| Original language | English |
|---|---|
| Pages (from-to) | 305-306 |
| Number of pages | 2 |
| Journal | Russian Journal of Physical Chemistry A |
| Volume | 78 |
| Issue number | 2 |
| Publication status | Published - Feb 2004 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
Cite this
Gas-chromatographic separation of enantiomers of amino acid trimethylsilyl derivatives on a chelate-containing immobile phase. / Slizhov, Yu G.; Gavrilenko, M. A.; Losev, A. G.
In: Russian Journal of Physical Chemistry A, Vol. 78, No. 2, 02.2004, p. 305-306.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Gas-chromatographic separation of enantiomers of amino acid trimethylsilyl derivatives on a chelate-containing immobile phase
AU - Slizhov, Yu G.
AU - Gavrilenko, M. A.
AU - Losev, A. G.
PY - 2004/2
Y1 - 2004/2
N2 - The chromatographic properties of zirconium(IV) acetylacetonate with grafted L-arginine were studied. The thermodynamic parameters of the retention of enantiomers of trimethylsilyl derivatives of amino acids on this stationary phase were determined. It was shown that the energy difference of sorbate-sorbent complexation is high enough to separate racemic mixtures.
AB - The chromatographic properties of zirconium(IV) acetylacetonate with grafted L-arginine were studied. The thermodynamic parameters of the retention of enantiomers of trimethylsilyl derivatives of amino acids on this stationary phase were determined. It was shown that the energy difference of sorbate-sorbent complexation is high enough to separate racemic mixtures.
UR - http://www.scopus.com/inward/record.url?scp=1642314514&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=1642314514&partnerID=8YFLogxK
M3 - Article
VL - 78
SP - 305
EP - 306
JO - Russian Journal of Physical Chemistry A
JF - Russian Journal of Physical Chemistry A
SN - 0036-0244
IS - 2
ER -