Gas-chromatographic separation of enantiomers of amino acid trimethylsilyl derivatives on a chelate-containing immobile phase

Abstract

The chromatographic properties of zirconium(IV) acetylacetonate with grafted L-arginine were studied. The thermodynamic parameters of the retention of enantiomers of trimethylsilyl derivatives of amino acids on this stationary phase were determined. It was shown that the energy difference of sorbate-sorbent complexation is high enough to separate racemic mixtures.

Original language	English
Pages (from-to)	305-306
Number of pages	2
Journal	Russian Journal of Physical Chemistry A
Volume	78
Issue number	2
Publication status	Published - Feb 2004

ASJC Scopus subject areas

Physical and Theoretical Chemistry

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title = "Gas-chromatographic separation of enantiomers of amino acid trimethylsilyl derivatives on a chelate-containing immobile phase",

abstract = "The chromatographic properties of zirconium(IV) acetylacetonate with grafted L-arginine were studied. The thermodynamic parameters of the retention of enantiomers of trimethylsilyl derivatives of amino acids on this stationary phase were determined. It was shown that the energy difference of sorbate-sorbent complexation is high enough to separate racemic mixtures.",

author = "Slizhov, {Yu G.} and Gavrilenko, {M. A.} and Losev, {A. G.}",

year = "2004",

month = feb,

language = "English",

volume = "78",

pages = "305--306",

journal = "Russian Journal of Physical Chemistry A",

issn = "0036-0244",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "2",

}

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T1 - Gas-chromatographic separation of enantiomers of amino acid trimethylsilyl derivatives on a chelate-containing immobile phase

AU - Slizhov, Yu G.

AU - Gavrilenko, M. A.

AU - Losev, A. G.

PY - 2004/2

Y1 - 2004/2

N2 - The chromatographic properties of zirconium(IV) acetylacetonate with grafted L-arginine were studied. The thermodynamic parameters of the retention of enantiomers of trimethylsilyl derivatives of amino acids on this stationary phase were determined. It was shown that the energy difference of sorbate-sorbent complexation is high enough to separate racemic mixtures.

AB - The chromatographic properties of zirconium(IV) acetylacetonate with grafted L-arginine were studied. The thermodynamic parameters of the retention of enantiomers of trimethylsilyl derivatives of amino acids on this stationary phase were determined. It was shown that the energy difference of sorbate-sorbent complexation is high enough to separate racemic mixtures.

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M3 - Article

AN - SCOPUS:1642314514

VL - 78

SP - 305

EP - 306

JO - Russian Journal of Physical Chemistry A

JF - Russian Journal of Physical Chemistry A

SN - 0036-0244

IS - 2

ER -