Formation of associates of solvated cations in salt solutions in polar dielectric liquids

M. A. Kazaryan, I. V. Shamanin, I. V. Lomov, S. Yu Dolgopolov, A. N. Lobanov

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Abstract

Experimental results are presented on excitation of oscillations of polarization charges of solvated ions in an aqueous solution of a mixture of cerium and lead nitrates under an external asymmetric electric field and the directed motion of solvated cerium and lead cations, caused by this process. The applicability of the approximation of the existence of a self-consistent electric field in the solution volume to explain the observed frequency ranges of the manifestation of the effect of electroinduced selective drift of solvated cations is demonstrated. The results of a theoretical analysis of the possibility of forming associates from solvated ions are presented.

Original language	English
Pages (from-to)	247-254
Number of pages	8
Journal	Bulletin of the Lebedev Physics Institute
Volume	38
Issue number	9
DOIs	https://doi.org/10.3103/S1068335611090016
Publication status	Published - Sep 2011

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Keywords

dielectric liquids
induced selective drift
solvated ions

ASJC Scopus subject areas

Physics and Astronomy(all)

Cite this

Kazaryan, M. A., Shamanin, I. V., Lomov, I. V., Dolgopolov, S. Y., & Lobanov, A. N. (2011). Formation of associates of solvated cations in salt solutions in polar dielectric liquids. Bulletin of the Lebedev Physics Institute, 38(9), 247-254. https://doi.org/10.3103/S1068335611090016

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AU - Shamanin, I. V.

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AU - Dolgopolov, S. Yu

AU - Lobanov, A. N.

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AB - Experimental results are presented on excitation of oscillations of polarization charges of solvated ions in an aqueous solution of a mixture of cerium and lead nitrates under an external asymmetric electric field and the directed motion of solvated cerium and lead cations, caused by this process. The applicability of the approximation of the existence of a self-consistent electric field in the solution volume to explain the observed frequency ranges of the manifestation of the effect of electroinduced selective drift of solvated cations is demonstrated. The results of a theoretical analysis of the possibility of forming associates from solvated ions are presented.

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KW - solvated ions

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10.3103/S1068335611090016