Formation of associates of solvated cations in salt solutions in polar dielectric liquids

Abstract

Experimental results are presented on excitation of oscillations of polarization charges of solvated ions in an aqueous solution of a mixture of cerium and lead nitrates under an external asymmetric electric field and the directed motion of solvated cerium and lead cations, caused by this process. The applicability of the approximation of the existence of a self-consistent electric field in the solution volume to explain the observed frequency ranges of the manifestation of the effect of electroinduced selective drift of solvated cations is demonstrated. The results of a theoretical analysis of the possibility of forming associates from solvated ions are presented.

Original language	English
Pages (from-to)	247-254
Number of pages	8
Journal	Bulletin of the Lebedev Physics Institute
Volume	38
Issue number	9
DOIs	https://doi.org/10.3103/S1068335611090016
Publication status	Published - Sep 2011

Keywords

dielectric liquids
induced selective drift
solvated ions

ASJC Scopus subject areas

Physics and Astronomy(all)

Access to Document

10.3103/S1068335611090016

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title = "Formation of associates of solvated cations in salt solutions in polar dielectric liquids",

abstract = "Experimental results are presented on excitation of oscillations of polarization charges of solvated ions in an aqueous solution of a mixture of cerium and lead nitrates under an external asymmetric electric field and the directed motion of solvated cerium and lead cations, caused by this process. The applicability of the approximation of the existence of a self-consistent electric field in the solution volume to explain the observed frequency ranges of the manifestation of the effect of electroinduced selective drift of solvated cations is demonstrated. The results of a theoretical analysis of the possibility of forming associates from solvated ions are presented.",

keywords = "dielectric liquids, induced selective drift, solvated ions",

author = "Kazaryan, {M. A.} and Shamanin, {I. V.} and Lomov, {I. V.} and Dolgopolov, {S. Yu} and Lobanov, {A. N.}",

year = "2011",

month = sep,

doi = "10.3103/S1068335611090016",

language = "English",

volume = "38",

pages = "247--254",

journal = "Bulletin of the Lebedev Physics Institute",

issn = "1068-3356",

publisher = "Springer Science + Business Media",

number = "9",

}

TY - JOUR

T1 - Formation of associates of solvated cations in salt solutions in polar dielectric liquids

AU - Kazaryan, M. A.

AU - Shamanin, I. V.

AU - Lomov, I. V.

AU - Dolgopolov, S. Yu

AU - Lobanov, A. N.

PY - 2011/9

Y1 - 2011/9

N2 - Experimental results are presented on excitation of oscillations of polarization charges of solvated ions in an aqueous solution of a mixture of cerium and lead nitrates under an external asymmetric electric field and the directed motion of solvated cerium and lead cations, caused by this process. The applicability of the approximation of the existence of a self-consistent electric field in the solution volume to explain the observed frequency ranges of the manifestation of the effect of electroinduced selective drift of solvated cations is demonstrated. The results of a theoretical analysis of the possibility of forming associates from solvated ions are presented.

AB - Experimental results are presented on excitation of oscillations of polarization charges of solvated ions in an aqueous solution of a mixture of cerium and lead nitrates under an external asymmetric electric field and the directed motion of solvated cerium and lead cations, caused by this process. The applicability of the approximation of the existence of a self-consistent electric field in the solution volume to explain the observed frequency ranges of the manifestation of the effect of electroinduced selective drift of solvated cations is demonstrated. The results of a theoretical analysis of the possibility of forming associates from solvated ions are presented.

KW - dielectric liquids

KW - induced selective drift

KW - solvated ions

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SP - 247

EP - 254

JO - Bulletin of the Lebedev Physics Institute

JF - Bulletin of the Lebedev Physics Institute

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