Formation of anode supported thin film YSZ electrolyte for ITSOFC by magnetron sputtering in the combination with pulsed electron-beam treatment

A. V. Shipilova, A. A. Soloviev, N. S. Sochugov, V. P. Rotshtein, S. V. Rabotkin

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

We describe a method of obtaining anode-supported ZrO2:Y2O3 (YSZ) electrolyte films produced by reactive magnetron sputtering for intermediate temperature solid oxide fuel cell applications. A pulsed electron beam treatment was used as a method of preliminary modification of the porous structure in anode substrates. The influence of this pretreatment on the gas tightness, structural and electrochemical properties of deposited films was studied. It is shown that magnetron sputtering combined with a pulsed electron-beam treatment lead to the formation of deposited YSZ films with a fine microstructure and improvement of electrochemical properties. For the electrolyte thickness about 2.5 μm and the gas permeability value of anode/electrolyte structure of 1.01×10-7 mol/m2s Pa, the maximum power density achieved for a single cell at 800°C and 650°C was found to be 610 and 220 mW/cm2 in air, respectively.
Original languageEnglish
Title of host publicationEFC 2011 - Proceedings of the 4th European Fuel Cell Piero Lunghi Conference and Exhibition
Pages39-40
Number of pages2
Publication statusPublished - 1 Jan 2011

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yttria-stabilized zirconia
magnetron sputtering
anodes
electrolytes
electron beams
thin films
tightness
solid oxide fuel cells
gases
pretreatment
radiant flux density
permeability
microstructure
air
cells
temperature

Cite this

Shipilova, A. V., Soloviev, A. A., Sochugov, N. S., Rotshtein, V. P., & Rabotkin, S. V. (2011). Formation of anode supported thin film YSZ electrolyte for ITSOFC by magnetron sputtering in the combination with pulsed electron-beam treatment. In EFC 2011 - Proceedings of the 4th European Fuel Cell Piero Lunghi Conference and Exhibition (pp. 39-40)

Formation of anode supported thin film YSZ electrolyte for ITSOFC by magnetron sputtering in the combination with pulsed electron-beam treatment. / Shipilova, A. V.; Soloviev, A. A.; Sochugov, N. S.; Rotshtein, V. P.; Rabotkin, S. V.

EFC 2011 - Proceedings of the 4th European Fuel Cell Piero Lunghi Conference and Exhibition. 2011. p. 39-40.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Shipilova, AV, Soloviev, AA, Sochugov, NS, Rotshtein, VP & Rabotkin, SV 2011, Formation of anode supported thin film YSZ electrolyte for ITSOFC by magnetron sputtering in the combination with pulsed electron-beam treatment. in EFC 2011 - Proceedings of the 4th European Fuel Cell Piero Lunghi Conference and Exhibition. pp. 39-40.
Shipilova AV, Soloviev AA, Sochugov NS, Rotshtein VP, Rabotkin SV. Formation of anode supported thin film YSZ electrolyte for ITSOFC by magnetron sputtering in the combination with pulsed electron-beam treatment. In EFC 2011 - Proceedings of the 4th European Fuel Cell Piero Lunghi Conference and Exhibition. 2011. p. 39-40
Shipilova, A. V. ; Soloviev, A. A. ; Sochugov, N. S. ; Rotshtein, V. P. ; Rabotkin, S. V. / Formation of anode supported thin film YSZ electrolyte for ITSOFC by magnetron sputtering in the combination with pulsed electron-beam treatment. EFC 2011 - Proceedings of the 4th European Fuel Cell Piero Lunghi Conference and Exhibition. 2011. pp. 39-40
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AU - Rotshtein, V. P.

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