Fluorination of beryllium concentrates with ammonium fluorides

A. A. Andreev, A. N. D'yachenko, R. I. Kraidenko

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

New method for processing of beryllium ores to beryllium oxide was suggested and studied. The method is based on decomposition of bertrandite or phenacite with ammonium chloride, with the subsequent leaching of ammonium tetrafluoroberyllate and precipitation from a beryllium hydroxide solution. The thermodynamic characteristics were calculated and a thermogravimetric analysis of the process was made. The kinetics of beryllium oxide fluorination with ammonium fluoride was experimentally studied. A technological scheme of a closed cycle for processing of beryllium-containing raw materials with ammonium fluoride was suggested.

Original languageEnglish
Pages (from-to)178-182
Number of pages5
JournalRussian Journal of Applied Chemistry
Volume81
Issue number2
DOIs
Publication statusPublished - Feb 2008

Fingerprint

Beryllium
Fluorination
Beryllia
Ammonium Chloride
Processing
Ammonium Compounds
Ores
Leaching
Thermogravimetric analysis
Raw materials
Thermodynamics
Decomposition
Kinetics
ammonium fluoride
beryllium oxide
beryllium hydroxide

ASJC Scopus subject areas

  • Chemistry (miscellaneous)

Cite this

Fluorination of beryllium concentrates with ammonium fluorides. / Andreev, A. A.; D'yachenko, A. N.; Kraidenko, R. I.

In: Russian Journal of Applied Chemistry, Vol. 81, No. 2, 02.2008, p. 178-182.

Research output: Contribution to journalArticle

Andreev, A. A. ; D'yachenko, A. N. ; Kraidenko, R. I. / Fluorination of beryllium concentrates with ammonium fluorides. In: Russian Journal of Applied Chemistry. 2008 ; Vol. 81, No. 2. pp. 178-182.
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