Flexible antibacterial Al-Cu-N films

J. Musil, J. Blažek, K. Fajfrlík, R. Čerstvý

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The paper reports on the effect of Cu content in the Al-Cu-N film on its antibacterial activity and mechanical properties. The Al-Cu-N films were prepared by reactive magnetron sputtering from composed Al/Cu targets using a dual magnetron. The antibacterial activity of Al-Cu-N films was tested on the killing of Escherichia coli bacteria. Mechanical properties of Al-Cu-N films were determined from the load vs. displacement curves measured by a Fischerscope H 100 microhardness tester. Mechanical properties were controlled by (i) the Cu content in the film and (ii) the energy Ei delivered to growing film by bombarding ions and fast neutrals. Correlations between the energy Ei, the content of Cu in the Al-Cu-N film and its mechanical and antibacterial properties were investigated in detail. It was found that (1) Al-Cu-N films with Cu content ranging from ~2 to ~12at.% exhibit (i) high hardness H ranging from ~15 to ~23GPa, (ii) high ratio H/E*≥0.1, (iii) high elastic recovery We≥60%, (iv) compressive macrostress (σ<0) and (v) enhanced resistance to cracking and (2) the Al-Cu-N films with≥7at.% Cu exhibit 100% efficiency of killing Ek of E. coli bacteria on their surface both in the daylight and in the dark. It means that the Al-Cu-N films sputtered under ion bombardment are three-functional antibacterial/flexible/protective films. Both the mechanical and antibacterial properties of sputtered Al-Cu-N films are described in detail.

Original languageEnglish
Pages (from-to)114-120
Number of pages7
JournalSurface and Coatings Technology
Volume264
DOIs
Publication statusPublished - 25 Feb 2015

Fingerprint

mechanical properties
Mechanical properties
Escherichia coli
Bacteria
bacteria
Reactive sputtering
Protective coatings
Film growth
Ion bombardment
Magnetron sputtering
Microhardness
Escherichia
test equipment
microhardness
Hardness
bombardment
Ions
magnetron sputtering
ions
hardness

Keywords

  • Al-Cu-N film
  • Antibacterial properties
  • Mechanical properties
  • Reactive magnetron sputtering
  • Resistance to cracking
  • Three-functional film

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

Flexible antibacterial Al-Cu-N films. / Musil, J.; Blažek, J.; Fajfrlík, K.; Čerstvý, R.

In: Surface and Coatings Technology, Vol. 264, 25.02.2015, p. 114-120.

Research output: Contribution to journalArticle

Musil, J. ; Blažek, J. ; Fajfrlík, K. ; Čerstvý, R. / Flexible antibacterial Al-Cu-N films. In: Surface and Coatings Technology. 2015 ; Vol. 264. pp. 114-120.
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