TY - JOUR
T1 - First study of the ro-vibrational structure of the g-symmetry vibrational states of C2D4 from the analysis of hot bands
T2 - The ν7+ν10−ν10 and ν10+ν12−ν10 bands
AU - Ulenikov, O. N.
AU - Gromova, O. V.
AU - Bekhtereva, E. S.
AU - Fomchenko, A. L.
AU - Sydow, C.
AU - Maul, C.
AU - Bauerecker, S.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - The two strongest absorption “hot” bands of C2D4, ν7+ν10−ν10 and ν10+ν12−ν10 were analyzed for the first time on the basis of high resolution infrared spectra recorded with a Bruker high resolution Fourier transform spectrometer. About 740 and 550 transitions (233 and 174 upper state ro-vibrational energy values) with Jmax.=25, Ka max=18 and Jmax.=20, Ka max.=10 for the bands ν7+ν10−ν10 and ν10+ν12−ν10 were assigned. The obtained upper ro-vibrational energies were used then in the weighted fit of parameters of the effective Hamiltonian which takes into account resonance interactions between the vibrational states (v7=v10=1) and (v10=v12=1), on the one hand, and eight other closely located vibrational states, on the other hand. A set of 46 varied parameters was obtained from the fit, which reproduces the initial experimental data with the rms deviation of 2.5×10−4cm−1 and which is close to experimental uncertainties.
AB - The two strongest absorption “hot” bands of C2D4, ν7+ν10−ν10 and ν10+ν12−ν10 were analyzed for the first time on the basis of high resolution infrared spectra recorded with a Bruker high resolution Fourier transform spectrometer. About 740 and 550 transitions (233 and 174 upper state ro-vibrational energy values) with Jmax.=25, Ka max=18 and Jmax.=20, Ka max.=10 for the bands ν7+ν10−ν10 and ν10+ν12−ν10 were assigned. The obtained upper ro-vibrational energies were used then in the weighted fit of parameters of the effective Hamiltonian which takes into account resonance interactions between the vibrational states (v7=v10=1) and (v10=v12=1), on the one hand, and eight other closely located vibrational states, on the other hand. A set of 46 varied parameters was obtained from the fit, which reproduces the initial experimental data with the rms deviation of 2.5×10−4cm−1 and which is close to experimental uncertainties.
KW - C2D4
KW - High-resolution spectra
KW - Hot band
KW - Spectroscopic parameters
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U2 - 10.1016/j.jqsrt.2016.09.014
DO - 10.1016/j.jqsrt.2016.09.014
M3 - Article
AN - SCOPUS:84991704702
VL - 187
SP - 178
EP - 189
JO - Journal of Quantitative Spectroscopy and Radiative Transfer
JF - Journal of Quantitative Spectroscopy and Radiative Transfer
SN - 0022-4073
ER -