First high-resolution study of the 13CHD3 infrared spectrum

Rotational analysis of the ground state and the fundamentals ν5 and ν3/v6

O. N. Ulenikov, G. A. Onopenko, S. Alanko, M. Koivusaari, R. Anttila

Research output: Contribution to journalArticle

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Abstract

The rotational structure in three fundamental bands ν3, νs, and ν6 of 13CHD3 has been analyzed. As this study evidently is the first high-resolution investigation on the spectrum of this molecule, the determination of the ground state rotational constants was the necessary first step. The ν5 band (1290.536 cm-1) could be treated as an isolated band whereas it was necessary to analyze the bands ν3 (994.713 cm-1) and ν6 (1030.243 cm-1) simultaneously because of very strong interactions. The total number of assigned lines was 1116. The spectral region 850-1530 cm-1 was measured on a Fourier transform spectrometer and the 13C species was in natural abundance in CHD3.

Original languageEnglish
Pages (from-to)9-16
Number of pages8
JournalJournal of Molecular Spectroscopy
Volume191
Issue number1
DOIs
Publication statusPublished - 1 Jan 1998

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Ground state
Spectrometers
Fourier transforms
infrared spectra
Infrared radiation
Molecules
ground state
high resolution
spectrometers
molecules

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

Cite this

First high-resolution study of the 13CHD3 infrared spectrum : Rotational analysis of the ground state and the fundamentals ν5 and ν3/v6. / Ulenikov, O. N.; Onopenko, G. A.; Alanko, S.; Koivusaari, M.; Anttila, R.

In: Journal of Molecular Spectroscopy, Vol. 191, No. 1, 01.01.1998, p. 9-16.

Research output: Contribution to journalArticle

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