First high-resolution analysis of the 3ν4, ν2+2ν4 and 2ν24 bands of 76GeH4

O. N. Ulenikov, O. V. Gromova, E. S. Bekhtereva, N. I. Raspopova, I. A. Velmuzhova, M. A. Koshelev, P. G. Sennikov

Research output: Contribution to journalArticlepeer-review

Abstract

The infrared spectrum of germane, purified and enriched up to 88.1% of 76GeH4, was measured at the temperature of (22.6±0.1)C with a Bruker Fourier transform infrared spectrometer IFS125HR and analyzed in the region of 2350–2730 cm−1 where the bending tetrad of the ro-vibrational octad of germane is located. The 2955 transitions belonging to the thirteen sub-bands of the Tetrad were assigned and theoretically analysed in the frame of the effective Hamiltonian model. The obtained set of 98 fitted parameters reproduces the initial 2955 experimental line positions with the drms=6.43×10−4 cm−1. A list of assigned experimental transitions is presented as the Supplementary material to the present paper.

Original languageEnglish
Article number107517
JournalJournal of Quantitative Spectroscopy and Radiative Transfer
Volume262
DOIs
Publication statusPublished - Mar 2021

Keywords

  • determination of spectroscopic parameters
  • resonance interactions in spherical top molecules
  • The 3v4/v2+2v4/2v2+v4 interacting states of GeH4

ASJC Scopus subject areas

  • Radiation
  • Atomic and Molecular Physics, and Optics
  • Spectroscopy

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