Fickian Diffusion in Ternary Mixtures Composed by 1,2,3,4-Tetrahydronaphthalene, Isobutylbenzene, and n-Dodecane

V. Sechenyh, J. C. Legros, A. Mialdun, J. M. Ortiz De Zárate, V. Shevtsova

    Research output: Contribution to journalArticle

    21 Citations (Scopus)

    Abstract

    We report the Fickian diffusion coefficients in 20 ternary mixtures formed by 1,2,3,4-tetrahydronaphthalene (THN), isobutylbenzene (IBB) and n-dodecane (nC12) measured by the Taylor dispersion technique at 298.1 K and atmospheric pressure. Four diffusion coefficients of the ternary mixtures were measured along six concentration paths starting on one binary subsystem and moving toward the other one. We found expressions for the diffusion matrix of a ternary mixture approaching to the binary limits. The measured diffusion coefficients were thoroughly verified by comparison with the theoretical asymptotic behavior. The main diffusion coefficients vary smoothly over the entire concentration space and D11 is always larger than D22. One of the two cross-diffusion coefficients is of the same order of magnitude as the main ones and, hence, not negligible, whereas the other one is close to zero. The investigated mixtures also comprise compositions that were examined in microgravity experiments in the ESA DCMIX1 project.

    Original languageEnglish
    Pages (from-to)535-548
    Number of pages14
    JournalJournal of Physical Chemistry B
    Volume120
    Issue number3
    DOIs
    Publication statusPublished - 28 Jan 2016

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    diffusion coefficient
    microgravity
    European Space Agency
    Microgravity
    atmospheric pressure
    Atmospheric pressure
    tetralin
    n-dodecane
    matrices
    Chemical analysis
    Experiments

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Materials Chemistry
    • Surfaces, Coatings and Films

    Cite this

    Fickian Diffusion in Ternary Mixtures Composed by 1,2,3,4-Tetrahydronaphthalene, Isobutylbenzene, and n-Dodecane. / Sechenyh, V.; Legros, J. C.; Mialdun, A.; Ortiz De Zárate, J. M.; Shevtsova, V.

    In: Journal of Physical Chemistry B, Vol. 120, No. 3, 28.01.2016, p. 535-548.

    Research output: Contribution to journalArticle

    Sechenyh, V. ; Legros, J. C. ; Mialdun, A. ; Ortiz De Zárate, J. M. ; Shevtsova, V. / Fickian Diffusion in Ternary Mixtures Composed by 1,2,3,4-Tetrahydronaphthalene, Isobutylbenzene, and n-Dodecane. In: Journal of Physical Chemistry B. 2016 ; Vol. 120, No. 3. pp. 535-548.
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    abstract = "We report the Fickian diffusion coefficients in 20 ternary mixtures formed by 1,2,3,4-tetrahydronaphthalene (THN), isobutylbenzene (IBB) and n-dodecane (nC12) measured by the Taylor dispersion technique at 298.1 K and atmospheric pressure. Four diffusion coefficients of the ternary mixtures were measured along six concentration paths starting on one binary subsystem and moving toward the other one. We found expressions for the diffusion matrix of a ternary mixture approaching to the binary limits. The measured diffusion coefficients were thoroughly verified by comparison with the theoretical asymptotic behavior. The main diffusion coefficients vary smoothly over the entire concentration space and D11 is always larger than D22. One of the two cross-diffusion coefficients is of the same order of magnitude as the main ones and, hence, not negligible, whereas the other one is close to zero. The investigated mixtures also comprise compositions that were examined in microgravity experiments in the ESA DCMIX1 project.",
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    AU - Legros, J. C.

    AU - Mialdun, A.

    AU - Ortiz De Zárate, J. M.

    AU - Shevtsova, V.

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