Facile One-Pot Synthesis of Diaryliodonium Salts from Arenes and Aryl Iodides with Oxone

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7 Citations (Scopus)

Abstract

A straightforward synthesis of diaryliodonium salts is achieved by using Oxone as the stoichiometric oxidant. Slow addition is the key to obtaining good yields and purities of the reaction products, which are highly useful reagents in many different areas of organic synthesis.

Original languageEnglish
Pages (from-to)18-20
Number of pages3
JournalChemistryOpen
Volume6
Issue number1
DOIs
Publication statusPublished - 1 Feb 2017
Externally publishedYes

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Iodides
Salts
Reaction products
Oxidants
potassium peroxymonosulfuric acid

Keywords

  • diaryliodonium triflates
  • diaryliodonium trifluoroacetates
  • iodine(III) compounds
  • oxidation
  • synthesis

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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abstract = "A straightforward synthesis of diaryliodonium salts is achieved by using Oxone as the stoichiometric oxidant. Slow addition is the key to obtaining good yields and purities of the reaction products, which are highly useful reagents in many different areas of organic synthesis.",
keywords = "diaryliodonium triflates, diaryliodonium trifluoroacetates, iodine(III) compounds, oxidation, synthesis",
author = "Natalia Soldatova and Pavel Postnikov and Kukurina, {Olga S.} and Zhdankin, {Viktor V.} and Akira Yoshimura and Thomas Wirth and Yusubov, {Mekhman S.}",
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AU - Soldatova, Natalia

AU - Postnikov, Pavel

AU - Kukurina, Olga S.

AU - Zhdankin, Viktor V.

AU - Yoshimura, Akira

AU - Wirth, Thomas

AU - Yusubov, Mekhman S.

PY - 2017/2/1

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AB - A straightforward synthesis of diaryliodonium salts is achieved by using Oxone as the stoichiometric oxidant. Slow addition is the key to obtaining good yields and purities of the reaction products, which are highly useful reagents in many different areas of organic synthesis.

KW - diaryliodonium triflates

KW - diaryliodonium trifluoroacetates

KW - iodine(III) compounds

KW - oxidation

KW - synthesis

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