Abstract
The high resolution infrared spectra of SiD4 were recorded with Bruker IFS120 and IFS125 HR Fourier transform infrared spectrometers at an optical resolution of 0.002 and 0.0021 cm−1 and analyzed in the region of 1480–1700 cm−1 where the stretching bands ν3 and ν1 are located. The 2676 transitions with Jmax. = 44 were assigned to the ν3 band.The subsequent weighted fit of experimentally assigned transitions was made with the Hamiltonian model which takes the resonance interactions between the (0010) and (1000) vibrational states into account. As the result, a set of 18 fitted parameters was obtained which reproduces the initial 2676 ro–vibrational transitions with the drms=3.71×10−4 cm−1.
| Original language | English |
|---|---|
| Pages (from-to) | 224-237 |
| Number of pages | 14 |
| Journal | Journal of Quantitative Spectroscopy and Radiative Transfer |
| Volume | 219 |
| DOIs | |
| Publication status | Published - 1 Nov 2018 |
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Keywords
- energies, and spectroscopic parameters
- high resolution spectrum of SiD
- line positions in the v vibrational state
ASJC Scopus subject areas
- Radiation
- Atomic and Molecular Physics, and Optics
- Spectroscopy
Cite this
Extended analysis of the high–resolution spectrum of 28SiD4 in the region of the ν3 band. / Ulenikov, O. N.; Gromova, O. V.; Bekhtereva, E. S.; Raspopova, N. I.; Sydow, C.; Bauerecker, S.
In: Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 219, 01.11.2018, p. 224-237.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Extended analysis of the high–resolution spectrum of 28SiD4 in the region of the ν3 band
AU - Ulenikov, O. N.
AU - Gromova, O. V.
AU - Bekhtereva, E. S.
AU - Raspopova, N. I.
AU - Sydow, C.
AU - Bauerecker, S.
PY - 2018/11/1
Y1 - 2018/11/1
N2 - The high resolution infrared spectra of SiD4 were recorded with Bruker IFS120 and IFS125 HR Fourier transform infrared spectrometers at an optical resolution of 0.002 and 0.0021 cm−1 and analyzed in the region of 1480–1700 cm−1 where the stretching bands ν3 and ν1 are located. The 2676 transitions with Jmax. = 44 were assigned to the ν3 band.The subsequent weighted fit of experimentally assigned transitions was made with the Hamiltonian model which takes the resonance interactions between the (0010) and (1000) vibrational states into account. As the result, a set of 18 fitted parameters was obtained which reproduces the initial 2676 ro–vibrational transitions with the drms=3.71×10−4 cm−1.
AB - The high resolution infrared spectra of SiD4 were recorded with Bruker IFS120 and IFS125 HR Fourier transform infrared spectrometers at an optical resolution of 0.002 and 0.0021 cm−1 and analyzed in the region of 1480–1700 cm−1 where the stretching bands ν3 and ν1 are located. The 2676 transitions with Jmax. = 44 were assigned to the ν3 band.The subsequent weighted fit of experimentally assigned transitions was made with the Hamiltonian model which takes the resonance interactions between the (0010) and (1000) vibrational states into account. As the result, a set of 18 fitted parameters was obtained which reproduces the initial 2676 ro–vibrational transitions with the drms=3.71×10−4 cm−1.
KW - energies, and spectroscopic parameters
KW - high resolution spectrum of SiD
KW - line positions in the v vibrational state
UR - http://www.scopus.com/inward/record.url?scp=85052316801&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85052316801&partnerID=8YFLogxK
U2 - 10.1016/j.jqsrt.2018.08.012
DO - 10.1016/j.jqsrt.2018.08.012
M3 - Article
VL - 219
SP - 224
EP - 237
JO - Journal of Quantitative Spectroscopy and Radiative Transfer
JF - Journal of Quantitative Spectroscopy and Radiative Transfer
SN - 0022-4073
ER -