Experimental study of the reaction between epoxy compounds and titanium tetrachloride

E. P. Fiterer, V. G. Bondaletov, V. Ya Tolmacheva, L. V. Timoshenko

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Reactions between epoxy compounds (phenyl glycidyl ether and butyl glycidyl ether, epichlorohydrine and propylene oxide) and titanium tetrachloride are studied. Is shown that epoxy ring-opening leads to the formation of corresponding Ti-alkoxides in which OTi-group attaches to the secondary carbon atom. The synthesis of phenyl glycidyl ether in the phase-transfer catalysis conditions in the presence of quaternary ammonium salts in the aqueou alkali at room temperature is elaborated.

Original languageEnglish
Title of host publication8th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2004
Pages26-28
Number of pages3
Volume2
Publication statusPublished - 2004
Event8th Korea-Russia International Symposium on Science and Technology, KORUS 2004 - Tomsk, Russian Federation
Duration: 26 Jun 20043 Jul 2004

Other

Other8th Korea-Russia International Symposium on Science and Technology, KORUS 2004
CountryRussian Federation
CityTomsk
Period26.6.043.7.04

Fingerprint

Ethers
Titanium
Catalysis
Propylene
Salts
Atoms
Carbon
Oxides
Temperature

Keywords

  • Epoxides alkoxides
  • Glycidyl ether
  • Olefine oxides
  • Titanium tetrachloride

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Fiterer, E. P., Bondaletov, V. G., Tolmacheva, V. Y., & Timoshenko, L. V. (2004). Experimental study of the reaction between epoxy compounds and titanium tetrachloride. In 8th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2004 (Vol. 2, pp. 26-28)

Experimental study of the reaction between epoxy compounds and titanium tetrachloride. / Fiterer, E. P.; Bondaletov, V. G.; Tolmacheva, V. Ya; Timoshenko, L. V.

8th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2004. Vol. 2 2004. p. 26-28.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Fiterer, EP, Bondaletov, VG, Tolmacheva, VY & Timoshenko, LV 2004, Experimental study of the reaction between epoxy compounds and titanium tetrachloride. in 8th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2004. vol. 2, pp. 26-28, 8th Korea-Russia International Symposium on Science and Technology, KORUS 2004, Tomsk, Russian Federation, 26.6.04.
Fiterer EP, Bondaletov VG, Tolmacheva VY, Timoshenko LV. Experimental study of the reaction between epoxy compounds and titanium tetrachloride. In 8th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2004. Vol. 2. 2004. p. 26-28
Fiterer, E. P. ; Bondaletov, V. G. ; Tolmacheva, V. Ya ; Timoshenko, L. V. / Experimental study of the reaction between epoxy compounds and titanium tetrachloride. 8th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2004. Vol. 2 2004. pp. 26-28
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