Experimental study of the effect of metal nanopowders on the decomposition of HMX, AP and AN

Abstract

The effect of metal nanopowders (Al, Fe, W, Ni, Cu, and Cu-Ni alloys) on the decomposition of energetic materials (HMX, AP, and AN) with DTA-TGA method was studied and it was found that the catalytic action appears in the case of Cu-Ni nanopowders with the three studied energetic materials. The temperature of decomposition of energetic materials with the addition of metal nanopowders could be lowered by 82°C for AN, 161°C for AP, and 96°C for HMX. The reaction mechanism of metal nano-powders enhancing the decomposition of energetic materials is discussed.

Original language	English
Pages (from-to)	506-512
Number of pages	7
Journal	Propellants, Explosives, Pyrotechnics
Volume	34
Issue number	6
DOIs	https://doi.org/10.1002/prep.200800030
Publication status	Published - Dec 2009

Keywords

AN
AP
Decomposition
DTA-TGA
HMX
Metal nanopowders

ASJC Scopus subject areas

Chemical Engineering(all)
Chemistry(all)

Access to Document

10.1002/prep.200800030

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title = "Experimental study of the effect of metal nanopowders on the decomposition of HMX, AP and AN",

abstract = "The effect of metal nanopowders (Al, Fe, W, Ni, Cu, and Cu-Ni alloys) on the decomposition of energetic materials (HMX, AP, and AN) with DTA-TGA method was studied and it was found that the catalytic action appears in the case of Cu-Ni nanopowders with the three studied energetic materials. The temperature of decomposition of energetic materials with the addition of metal nanopowders could be lowered by 82°C for AN, 161°C for AP, and 96°C for HMX. The reaction mechanism of metal nano-powders enhancing the decomposition of energetic materials is discussed.",

keywords = "AN, AP, Decomposition, DTA-TGA, HMX, Metal nanopowders",

author = "Alexander Gromov and Yulia Strokova and Alexey Kabardin and Alexander Vorozhtsov and Ulrich Teipel",

year = "2009",

month = dec,

doi = "10.1002/prep.200800030",

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T1 - Experimental study of the effect of metal nanopowders on the decomposition of HMX, AP and AN

AU - Gromov, Alexander

AU - Strokova, Yulia

AU - Kabardin, Alexey

AU - Vorozhtsov, Alexander

AU - Teipel, Ulrich

PY - 2009/12

Y1 - 2009/12

N2 - The effect of metal nanopowders (Al, Fe, W, Ni, Cu, and Cu-Ni alloys) on the decomposition of energetic materials (HMX, AP, and AN) with DTA-TGA method was studied and it was found that the catalytic action appears in the case of Cu-Ni nanopowders with the three studied energetic materials. The temperature of decomposition of energetic materials with the addition of metal nanopowders could be lowered by 82°C for AN, 161°C for AP, and 96°C for HMX. The reaction mechanism of metal nano-powders enhancing the decomposition of energetic materials is discussed.

AB - The effect of metal nanopowders (Al, Fe, W, Ni, Cu, and Cu-Ni alloys) on the decomposition of energetic materials (HMX, AP, and AN) with DTA-TGA method was studied and it was found that the catalytic action appears in the case of Cu-Ni nanopowders with the three studied energetic materials. The temperature of decomposition of energetic materials with the addition of metal nanopowders could be lowered by 82°C for AN, 161°C for AP, and 96°C for HMX. The reaction mechanism of metal nano-powders enhancing the decomposition of energetic materials is discussed.

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KW - Decomposition

KW - DTA-TGA

KW - HMX

KW - Metal nanopowders

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